Gravitational collapse of depletion-induced colloidal gels

  • Wilson Poon (Creator)
  • Emanuela Zaccarelli (Creator)
  • Michiel Hermes (Creator)
  • R Harich (Creator)
  • T. W. Blythe (Creator)
  • A. J. Sederman (Creator)
  • L. F. Gladden (Creator)



We study the ageing and ultimate gravitational collapse of colloidal gels in which the interparticle attraction is induced by non-adsorbing polymers via the depletion effect. The gels are formed through arrested spinodal decomposition, whereby the dense phase arrests into an attractive glass. We map the experimental state diagram onto a theoretical one obtained from computer simulations and theoretical calculations. Discrepancies between the experimental and simulated gel regions in the state diagram can be explained by the particle size and density dependence of the boundary below which the gel is not strong enough to resist gravitational stress. Visual observations show that gravitational collapse of the gels concentrations showing the onset of rapid collapse after a delay time. Magnetic resonance imaging (MRI) was used to provide quantitative, spatio-temporally resolved measurements of the solid volume fraction in these rapidly collapsing gels. We find that during the delay time, a dense region builds up at the top of the falls into two distinct regimes as the colloid and polymer concentrations are varied, with gels at low colloid sample. The rapid collapse is initiated when the gel structure is no longer able to support this dense layer.

Data Citation

Harich, R.; Blythe, T.W.; Hermes, M.; Zaccarelli, E.; Sederman, A.J.; Gladden, L.F.; Poon, W.C.K.. (2015). Gravitational collapse of depletion-induced colloidal gels, [dataset].
Date made available21 Oct 2015
PublisherEdinburgh DataShare

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