Michael Ingleson

2024

Transition Metal‐Free Catalytic C−H Zincation and Alumination

Bisai, M., Losiewicz, J., Sotorrios, L., Nichol, G., Dominey, A., Cowley, M., Thomas, S., Macgregor, S. A. & Ingleson, M., 5 Apr 2024, (E-pub ahead of print) In: Angewandte Chemie International Edition. e202404848.

Research output: Contribution to journal › Article › peer-review

Open Access

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2023

Borylation–Reduction–Borylation for the Formation of 1,4-Azaborines

Kothavale, S. S., Iqbal, S. A., Hanover, E. L., Gupta, A. K., Zysman-Colman, E. & Ingleson, M. J., 6 Dec 2023, (E-pub ahead of print) In: Organic letters.

Research output: Contribution to journal › Article › peer-review

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NacNac-zinc-pyridonate mediated ϵ-caprolactone ROP

Hughes, J. W. J., Babula, D. J., Stowers-Veitch, F., Yuan, K., Uzelac, M., Nichol, G. S., Ingleson, M. J. & Garden, J. A., 20 Nov 2023, (E-pub ahead of print) In: Dalton Transactions.

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Borylation directed borylation of N-alkyl anilines using iodine activated pyrazaboles

Millet, C. R. P., Noone, E., Schellbach, A. V., Pahl, J., Łosiewicz, J., Nichol, G. & Ingleson, M. J., 17 Oct 2023, (E-pub ahead of print) In: Chemical Science.

Research output: Contribution to journal › Article › peer-review

Open Access

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Brominated B1-Polycyclic Aromatic Hydrocarbons for the Synthesis of Deep-Red to Near-Infrared Delayed Fluorescence Emitters

Yuan, K., Gupta, A. K., Si, C., Uzelac, M., Zysman-Colman, E. & Ingleson, M. J., 27 Jul 2023, (E-pub ahead of print) In: Organic letters. 25, 31, p. 5880-5884

Research output: Contribution to journal › Article › peer-review

Open Access

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Main Group Catalyzed Arene Borylation: Challenges and Opportunities

Ingleson, M. J., 23 May 2023, (E-pub ahead of print) In: ACS Catalysis. p. 7691-7697

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Open Access

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Amides as modifiable directing groups in electrophilic borylation

Iqbal, S. A., Uzelac, M., Nawaz, I., Wang, Z., Jones, T. H., Yuan, K., Millet, C. R. P., Nichol, G. S., Chotana, G. A. & Ingleson, M. J., 15 Mar 2023, (E-pub ahead of print) In: Chemical Science.

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Open Access

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Haloboration of o‐Alkynyl Phenols Generates Halogenated Bicyclic‐Boronates

Yuan, K. & Ingleson, M., 1 Mar 2023, (E-pub ahead of print) In: Angewandte Chemie International Edition.

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Open Access

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Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C-H Borylation

Grundy, M. E., Sotorrios, L., Bisai, M. K., Yuan, K., Macgregor, S. A. & Ingleson, M. J., 30 Jan 2023, (E-pub ahead of print) In: ACS Catalysis. p. 2286-2294 9 p.

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Open Access

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2022

Two Directing Groups Used for Metal Catalysed Meta‐C–H Functionalisation Only Effect Ortho Electrophilic C–H Borylation

Iqbal, S. A., Millet, C. R. P., Pahl, J., Yuan, K. & Ingleson, M., 21 Oct 2022, (E-pub ahead of print) In: European Journal of Organic Chemistry. 2022, 44, e202200901.

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Open Access

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Synthesis of Electrophiles Derived from Dimeric Aminoboranes and Assessing Their Utility in the Borylation of π Nucleophiles

Millet, C. R. P., Pahl, J., Noone, E., Yuan, K., Nichol, G. S., Uzelac, M. & Ingleson, M. J., 14 Sept 2022, (E-pub ahead of print) In: Organometallics.

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Borylation Directed Borylation of Indoles Using Pyrazabole Electrophiles: A One‐Pot Route to C7‐Borylated‐Indolines

Pahl, J., Noone, E., Uzelac, M., Yuan, K. & Ingleson, M., 10 Jun 2022, (E-pub ahead of print) In: Angewandte Chemie International Edition.

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XtalFluor‐E effects the C3‐H sulfenylation of indoles to form di‐indole sulfides

Cironis, N., Yuan, K., Thomas, S. & Ingleson, M. J., 11 Feb 2022, (E-pub ahead of print) In: European Journal of Organic Chemistry.

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Developing organoboranes as phase transfer catalysts for nucleophilic fluorination using CsF

Kirschner, S., Peters, M., Uzelac, M., Yuan, K. & Ingleson, M. J., 9 Feb 2022, (E-pub ahead of print) In: Chemical Science.

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Open Access

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Enhanced N-directed electrophilic C-H borylation generates BN-[5]- and [6]helicenes with improved photophysical properties.

Yuan, K., Volland, D., Kirschner, S., Uzelac, M., Nichol, G. S., Nowak-krol, A. & Ingleson, M. J., 4 Jan 2022, (E-pub ahead of print) In: Chemical Science.

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Open Access

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2021

Formation of a hydride containing amido-zincate using pinacolborane

Uzelac, M., Yuan, K., Nichol, G. S. & Ingleson, M. J., 15 Sept 2021, (E-pub ahead of print) In: Dalton Transactions.

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Open Access

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Zinc catalysed electrophilic C–H borylation of heteroarenes

Grundy, M. E., Yuan, K., Nichol, G. S. & Ingleson, M. J., 13 May 2021, (E-pub ahead of print) In: Chemical Science. 9 p.

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Controlling selectivity in N-heterocycle directed borylation of indoles

Iqbal, S. A., Yuan, K., Cid, J., Pahl, J. & Ingleson, M. J., 11 Mar 2021, (E-pub ahead of print) In: Organic & Biomolecular chemistry. 19, 13, p. 2949-2958

Research output: Contribution to journal › Article › peer-review

Open Access

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2020

Haloboration: scope, mechanism and utility

Kirschner, S., Yuan, K. & Ingleson, M. J., 8 Jul 2020, (E-pub ahead of print) In: New journal of chemistry.

Research output: Contribution to journal › Article › peer-review

Open Access

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Intramolecular (directed) electrophilic C–H borylation

Iqbal, S. A., Pahl, J., Yuan, K. & Ingleson, M. J., 4 Jun 2020, (E-pub ahead of print) In: Chemical Society Reviews.

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A Comparison of Two Zinc Hydride Catalysts for Terminal Alkyne C–H Borylation/Hydroboration and the Formation of 1,1,1-Triborylalkanes by Tandem Catalysis Using Zn–H and B–H Compounds

Uzelac, M., Yuan, K. & Ingleson, M. J., 13 Apr 2020, (E-pub ahead of print) In: Organometallics.

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The synthesis of brominated-boron-doped PAHs by alkyne 1,1-bromoboration: mechanistic and functionalisation studies

Yuan, K., Kahan, R. J., Si, C., Williams, A., Kirschner, S., Uzelac, M., Zysman-colman, E. & Ingleson, M. J., 27 Feb 2020, (E-pub ahead of print) In: Chemical Science.

Research output: Contribution to journal › Article › peer-review

Open Access

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2019

Acyl Directed ortho-Borylation of Anilines and C7 Borylation of Indoles using just BBr3

Iqbal, S., Cid, J., Procter, R., Uzelac, M., Yuan, K. & Ingleson, M., 21 Oct 2019, In: Angewandte Chemie International Edition. 58, 43, p. 15381-15385 5 p.

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Borylative cyclisation of diynes using BCl3 and borocations

Warner, A. J., Enright, K. M., Cole, J. M., Yuan, K., Mcgough, J. S. & Ingleson, M. J., 20 May 2019, (E-pub ahead of print) In: Organic & Biomolecular chemistry.

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Low coordinate NHC-Zinc-Hydride Complexes Catalyze Alkyne C-H Borylation and Hydroboration using Pinacolborane

Procter, R. J., Uzelac, M., Cid, J., Rushworth, P. J. & Ingleson, M. J., 15 May 2019, (E-pub ahead of print) In: ACS Catalysis.

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Well-Defined Boron/Nitrogen-Doped Polycyclic Aromatic Hydrocarbons Are Active Electrocatalysts for the Oxygen Reduction Reaction

Kahan, R. J., Hirunpinyopas, W., Cid, J., Ingleson, M. J. & Dryfe, R. A. W., 26 Mar 2019, In: Chemistry of Materials. 31, 6, p. 1891-1898 8 p.

Research output: Contribution to journal › Article › peer-review

Benzoselenadiazole and benzotriazole directed electrophilic C-H borylation of conjugated donor-acceptor materials

Dash, B. P., Hamilton, I., Tate, D. J., Crossley, D. L., Kim, J. S., Ingleson, M. J. & Turner, M. L., 1 Jan 2019, In: Journal of Materials Chemistry C Materials for optical and electronic devices. 7, 3, p. 718-724 7 p.

Research output: Contribution to journal › Article › peer-review

2018

Reductive α-borylation of α,β-unsaturated esters using NHC-BH ₃ activated by I ₂ as a metal-free route to α-boryl esters

Radcliffe, J. E., Fasano, V., Adams, R. W., You, P. & Ingleson, M. J., 19 Nov 2018, (E-pub ahead of print) In: Chemical Science. 10, 5, p. 1434-1441 8 p.

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Phosphorous(v) Lewis acids: Water/base tolerant P₃-trimethylated trications

Bayne, J. M., Fasano, V., Szkop, K. M., Ingleson, M. J. & Stephan, D. W., 12 Oct 2018, (E-pub ahead of print) In: Chemical Communications. 54, 88, p. 12467-12470 4 p.

Research output: Contribution to journal › Article › peer-review

Selective Boryl-Anion Migration in a Vinyl sp²−sp³ Diborane Induced by Soft Borane Lewis Acids

Fasano, V., Cid, J., Procter, R. J., Ross, E. & Ingleson, M. J., 13 Aug 2018, (E-pub ahead of print) In: Angewandte Chemie - International Edition. 57, 40, p. 13293-13297 5 p.

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Generation of a series of B _n fused oligo-naphthalenes (n = 1 to 3) from a B ₁ -polycyclic aromatic hydrocarbon

Kahan, R. J., Crossley, D. L., Cid, J., Radcliffe, J. E., Woodward, A. W., Fasano, V., Endres, S., Whitehead, G. F. S. & Ingleson, M. J., 8 Aug 2018, (E-pub ahead of print) In: Chemical Communications. 54, 68, p. 9490-9493 4 p.

Research output: Contribution to journal › Article › peer-review

Diboryldiborenes: π-Conjugated B4 Chains Isoelectronic to the Butadiene Dication

Hermann, A., Cid, J., Mattock, J. D., Dewhurst, R. D., Krummenacher, I., Vargas, A., Ingleson, M. J. & Braunschweig, H., 6 Aug 2018, In: Angewandte Chemie - International Edition. 57, 32, p. 10091-10095 5 p.

Research output: Contribution to journal › Article › peer-review

Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations

Cid, J., Hermann, A., Radcliffe, J. E., Curless, L. D., Braunschweig, H. & Ingleson, M. J., 25 Jun 2018, In: Organometallics. 37, 12, p. 1992-1998 7 p.

Research output: Contribution to journal › Article › peer-review

C−H Borylation/Cross-Coupling Forms Twisted Donor–Acceptor Compounds Exhibiting Donor-Dependent Delayed Emission

Crossley, D. L., Kulapichitr, P., Radcliffe, J. E., Dunsford, J. J., Vitorica-Yrezabal, I., Kahan, R. J., Woodward, A. W., Turner, M. L., McDouall, J. J. W. & Ingleson, M. J., 21 May 2018, (E-pub ahead of print) In: Chemistry - A European Journal. 24, 41, p. 10521-10530 10 p.

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Open Access

Synthesis, Characterization, and Functionalization of 1-Boraphenalenes

Kahan, R. J., Crossley, D. L., Cid, J., Radcliffe, J. E. & Ingleson, M. J., 11 May 2018, (E-pub ahead of print) In: Angewandte Chemie - International Edition. 57, 27, p. 8084-8088 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Recent Advances in Water-Tolerance in Frustrated Lewis Pair Chemistry

Fasano, V. & Ingleson, M. J., 29 Mar 2018, (E-pub ahead of print) In: Synthesis (Germany). 50, 9, p. 1783-1795 13 p., ss-2018-z0059-sr.

Research output: Contribution to journal › Review article › peer-review

2017

Open Access

Post-polymerization C-H Borylation of Donor-Acceptor Materials Gives Highly Efficient Solid State Near-Infrared Emitters for Near-IR-OLEDs and Effective Biological Imaging

Crossley, D. L., Urbano, L., Neumann, R., Bourke, S., Jones, J., Dailey, L. A., Green, M., Humphries, M. J., King, S. M., Turner, M. L. & Ingleson, M. J., 30 Aug 2017, In: ACS Applied Materials and Interfaces. 9, 34, p. 28243-28249 7 p.

Research output: Contribution to journal › Article › peer-review

Borylated Arylamine-Benzothiadiazole Donor-Acceptor Materials as Low-LUMO, Low-Band-Gap Chromophores

Crossley, D. L., Goh, R., Cid, J., Vitorica-Yrezabal, I., Turner, M. L. & Ingleson, M. J., 24 Jul 2017, In: Organometallics. 36, 14, p. 2597-2604 8 p.

Research output: Contribution to journal › Article › peer-review

Use of N-methyliminodiacetic acid boronate esters in suzuki-miyaura cross-coupling polymerizations of triarylamine and fluorene monomers

Foster, A. B., Bagutski, V., Ayuso-Carrillo, J. I., Humphries, M. J., Ingleson, M. J. & Turner, M. L., 3 Jul 2017, (E-pub ahead of print) In: Journal of Polymer Science Part A: Polymer Chemistry. 55, 17, p. 2798-2806 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Frustrated Lewis Pair Mediated 1,2-Hydrocarbation of Alkynes

Fasano, V., Curless, L. D., Radcliffe, J. E. & Ingleson, M. J., 13 Jun 2017, (E-pub ahead of print) In: Angewandte Chemie - International Edition. 56, 31, p. 9202-9206 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2016

Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations

Fasano, V. & Ingleson, M. J., 15 Dec 2016, (E-pub ahead of print) In: Chemistry - A European Journal. 23, 9, p. 2217-2224 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

BCl₃-Induced Annulative Oxo- and Thioboration for the Formation of C3-Borylated Benzofurans and Benzothiophenes

Warner, A. J., Churn, A., McGough, J. S. & Ingleson, M. J., 29 Nov 2016, In: Angewandte Chemie - International Edition. 56, 1, p. 354-358 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ-Bond Activation and Catalytic (De)hydrosilylation

Fasano, V., Radcliffe, J. E., Curless, L. D. & Ingleson, M. J., 25 Oct 2016, (E-pub ahead of print) In: Chemistry - A European Journal. 23, 1, p. 187-193 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

A General Protocol for the Polycondensation of Thienyl N-Methyliminodiacetic Acid Boronate Esters to Form High Molecular Weight Copolymers

Carrillo, J. A., Turner, M. L. & Ingleson, M. J., 12 Oct 2016, In: Journal of the American Chemical Society. 138, 40, p. 13361-13368 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Michael Ingleson

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