1,1-Divinylallene

Katie M. Cergol; Christopher G. Newton; Andrew L. Lawrence; Anthony C. Willis; Michael N. Paddon-row; Michael S. Sherburn

doi:10.1002/anie.201105541

1,1-Divinylallene

Katie M. Cergol, Christopher G. Newton, Andrew L. Lawrence, Anthony C. Willis, Michael N. Paddon-row, Michael S. Sherburn

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

How to hit a triple: The title hydrocarbon, one of the most π-bond-rich small molecules, has been synthesized and characterized for the first time. This highly reactive hydrocarbon undergoes a new diene-transmissive, triple Diels–Alder cycloaddition sequence to form six new C[BOND]C bonds and the fused tricyclic phenalene ring system in one step. Controlled single additions have also been achieved.

Original language	English
Pages (from-to)	10425–10428
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	44
DOIs	https://doi.org/10.1002/anie.201105541
Publication status	Published - 24 Dec 2011

Keywords / Materials (for Non-textual outputs)

1,1-divinylallene
cycloaddition

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10.1002/anie.201105541

Cite this

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title = "1,1-Divinylallene",

abstract = "How to hit a triple: The title hydrocarbon, one of the most π-bond-rich small molecules, has been synthesized and characterized for the first time. This highly reactive hydrocarbon undergoes a new diene-transmissive, triple Diels–Alder cycloaddition sequence to form six new C[BOND]C bonds and the fused tricyclic phenalene ring system in one step. Controlled single additions have also been achieved.",

keywords = "1,1-divinylallene, cycloaddition",

author = "Cergol, {Katie M.} and Newton, {Christopher G.} and Lawrence, {Andrew L.} and Willis, {Anthony C.} and Paddon-row, {Michael N.} and Sherburn, {Michael S.}",

year = "2011",

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doi = "10.1002/anie.201105541",

language = "English",

volume = "50",

pages = "10425–10428",

journal = "Angewandte Chemie International Edition",

issn = "1521-3773",

publisher = "Wiley-VCH",

number = "44",

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T1 - 1,1-Divinylallene

AU - Cergol, Katie M.

AU - Newton, Christopher G.

AU - Lawrence, Andrew L.

AU - Willis, Anthony C.

AU - Paddon-row, Michael N.

AU - Sherburn, Michael S.

PY - 2011/12/24

Y1 - 2011/12/24

N2 - How to hit a triple: The title hydrocarbon, one of the most π-bond-rich small molecules, has been synthesized and characterized for the first time. This highly reactive hydrocarbon undergoes a new diene-transmissive, triple Diels–Alder cycloaddition sequence to form six new C[BOND]C bonds and the fused tricyclic phenalene ring system in one step. Controlled single additions have also been achieved.

AB - How to hit a triple: The title hydrocarbon, one of the most π-bond-rich small molecules, has been synthesized and characterized for the first time. This highly reactive hydrocarbon undergoes a new diene-transmissive, triple Diels–Alder cycloaddition sequence to form six new C[BOND]C bonds and the fused tricyclic phenalene ring system in one step. Controlled single additions have also been achieved.

KW - 1,1-divinylallene

KW - cycloaddition

U2 - 10.1002/anie.201105541

DO - 10.1002/anie.201105541

M3 - Article

AN - SCOPUS:80055012811

SN - 1521-3773

VL - 50

SP - 10425

EP - 10428

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 44

ER -

1,1-Divinylallene

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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