2-(2 '-Pyridyl)-4,6-diphenylphosphinine versus 2-(2 '-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

Ariadna Campos Carrasco; Evgeny A. Pidko; Anna M. Masdeu-Bulto; Martin Lutz; Anthony L. Spek; Dieter Vogt; Christian Muller

doi:10.1039/c0nj00030b

2-(2 '-Pyridyl)-4,6-diphenylphosphinine versus 2-(2 '-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

Ariadna Campos Carrasco, Evgeny A. Pidko, Anna M. Masdeu-Bulto, Martin Lutz, Anthony L. Spek, Dieter Vogt, Christian Muller

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Abstract / Description of output

The coordination chemistry of the bidentate P,N hybrid ligand 2-(2'-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2'-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L-2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

Original language	English
Pages (from-to)	1547-1550
Number of pages	4
Journal	New journal of chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1039/c0nj00030b
Publication status	Published - 2010

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title = "2-(2 '-Pyridyl)-4,6-diphenylphosphinine versus 2-(2 '-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)",

abstract = "The coordination chemistry of the bidentate P,N hybrid ligand 2-(2'-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2'-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L-2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.",

author = "{Campos Carrasco}, Ariadna and Pidko, {Evgeny A.} and Masdeu-Bulto, {Anna M.} and Martin Lutz and Spek, {Anthony L.} and Dieter Vogt and Christian Muller",

year = "2010",

doi = "10.1039/c0nj00030b",

language = "English",

volume = "34",

pages = "1547--1550",

journal = "New journal of chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

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T1 - 2-(2 '-Pyridyl)-4,6-diphenylphosphinine versus 2-(2 '-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

AU - Campos Carrasco, Ariadna

AU - Pidko, Evgeny A.

AU - Masdeu-Bulto, Anna M.

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Vogt, Dieter

AU - Muller, Christian

PY - 2010

Y1 - 2010

N2 - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2'-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2'-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L-2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

AB - The coordination chemistry of the bidentate P,N hybrid ligand 2-(2'-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2'-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L-2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

U2 - 10.1039/c0nj00030b

DO - 10.1039/c0nj00030b

M3 - Article

SN - 1144-0546

VL - 34

SP - 1547

EP - 1550

JO - New journal of chemistry

JF - New journal of chemistry

IS - 8

ER -

2-(2 '-Pyridyl)-4,6-diphenylphosphinine versus 2-(2 '-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

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