A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand

Jose Martinez-Lillo; Neil Dolan; Euan K. Brechin

doi:10.1039/c3dt51512e

A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand

Jose Martinez-Lillo^*, Neil Dolan, Euan K. Brechin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The salicylamidoxime-based complex [Mn-6(mu(3)-O)(2)(N-H2-sao)(6)(py)(6)(EtOH)(2)](ClO4)(2)center dot 4EtOH (1.4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn-6(III)] single-molecule magnets.

Original language	English
Pages (from-to)	12824-12827
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	36
DOIs	https://doi.org/10.1039/c3dt51512e
Publication status	Published - 2013

Keywords / Materials (for Non-textual outputs)

TARGETED STRUCTURAL DISTORTION
CHAIN MAGNETS
FAMILY

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title = "A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand",

abstract = "The salicylamidoxime-based complex [Mn-6(mu(3)-O)(2)(N-H2-sao)(6)(py)(6)(EtOH)(2)](ClO4)(2)center dot 4EtOH (1.4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn-6(III)] single-molecule magnets.",

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AU - Martinez-Lillo, Jose

AU - Dolan, Neil

AU - Brechin, Euan K.

PY - 2013

Y1 - 2013

N2 - The salicylamidoxime-based complex [Mn-6(mu(3)-O)(2)(N-H2-sao)(6)(py)(6)(EtOH)(2)](ClO4)(2)center dot 4EtOH (1.4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn-6(III)] single-molecule magnets.

AB - The salicylamidoxime-based complex [Mn-6(mu(3)-O)(2)(N-H2-sao)(6)(py)(6)(EtOH)(2)](ClO4)(2)center dot 4EtOH (1.4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn-6(III)] single-molecule magnets.

KW - TARGETED STRUCTURAL DISTORTION

KW - CHAIN MAGNETS

KW - FAMILY

U2 - 10.1039/c3dt51512e

DO - 10.1039/c3dt51512e

M3 - Article

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SN - 0300-9246

VL - 42

SP - 12824

EP - 12827

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand

Abstract

Keywords / Materials (for Non-textual outputs)

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