A cube in a tetrahedron: Microwave-assisted synthesis of an octametallic Fe-III cluster

Ian A. Gass; Constantinos J. Milios; A. Gavin Whittaker; Francesca P. A. Fabbiani; Simon Parsons; Mark Murrie; Spyros P. Perlepes; Euan K. Brechin

doi:10.1021/ic0607843

A cube in a tetrahedron: Microwave-assisted synthesis of an octametallic Fe-III cluster

Ian A. Gass, Constantinos J. Milios, A. Gavin Whittaker, Francesca P. A. Fabbiani, Simon Parsons, Mark Murrie, Spyros P. Perlepes, Euan K. Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

The microwave-assisted reaction of Fe(O2CMe)(2) with salicylaldoxime (saoH(2)) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao(2-) exhibits a novel coordination mode.

Original language	English
Pages (from-to)	5281-5283
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0607843
Publication status	Published - 10 Jul 2006

Keywords / Materials (for Non-textual outputs)

SINGLE-MOLECULE MAGNETS
SOLVOTHERMAL SYNTHESIS
COMPLEXES
CHEMISTRY
CORE
IRON
SALICYLALDOXIME
MANGANESE
NICKEL
ROUTES

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10.1021/ic0607843

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title = "A cube in a tetrahedron: Microwave-assisted synthesis of an octametallic Fe-III cluster",

abstract = "The microwave-assisted reaction of Fe(O2CMe)(2) with salicylaldoxime (saoH(2)) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao(2-) exhibits a novel coordination mode.",

keywords = "SINGLE-MOLECULE MAGNETS, SOLVOTHERMAL SYNTHESIS, COMPLEXES, CHEMISTRY, CORE, IRON, SALICYLALDOXIME, MANGANESE, NICKEL, ROUTES",

author = "Gass, {Ian A.} and Milios, {Constantinos J.} and Whittaker, {A. Gavin} and Fabbiani, {Francesca P. A.} and Simon Parsons and Mark Murrie and Perlepes, {Spyros P.} and Brechin, {Euan K.}",

year = "2006",

month = jul,

day = "10",

doi = "10.1021/ic0607843",

language = "English",

volume = "45",

pages = "5281--5283",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "14",

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TY - JOUR

T1 - A cube in a tetrahedron: Microwave-assisted synthesis of an octametallic Fe-III cluster

AU - Gass, Ian A.

AU - Milios, Constantinos J.

AU - Whittaker, A. Gavin

AU - Fabbiani, Francesca P. A.

AU - Parsons, Simon

AU - Murrie, Mark

AU - Perlepes, Spyros P.

AU - Brechin, Euan K.

PY - 2006/7/10

Y1 - 2006/7/10

N2 - The microwave-assisted reaction of Fe(O2CMe)(2) with salicylaldoxime (saoH(2)) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao(2-) exhibits a novel coordination mode.

AB - The microwave-assisted reaction of Fe(O2CMe)(2) with salicylaldoxime (saoH(2)) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao(2-) exhibits a novel coordination mode.

KW - SINGLE-MOLECULE MAGNETS

KW - SOLVOTHERMAL SYNTHESIS

KW - COMPLEXES

KW - CHEMISTRY

KW - CORE

KW - IRON

KW - SALICYLALDOXIME

KW - MANGANESE

KW - NICKEL

KW - ROUTES

U2 - 10.1021/ic0607843

DO - 10.1021/ic0607843

M3 - Article

SN - 0020-1669

VL - 45

SP - 5281

EP - 5283

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

A cube in a tetrahedron: Microwave-assisted synthesis of an octametallic Fe-III cluster

Abstract

Keywords / Materials (for Non-textual outputs)

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