A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment

Ahmed Yahia; Polly L. Arnold; Jason B. Love; Laurent Maron

doi:10.1039/b900571d

A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment

Ahmed Yahia, Polly L. Arnold, Jason B. Love, Laurent Maron

Research output: Contribution to journal › Article › peer-review

Abstract

A DFT study of the reduction and silylation of the uranyl U-O bond in a macrocyclic complex shows the importance of the initial dipotassiation in THF solution, and a slightly downhill reaction pathway for the oxo group functionalisation.

Original language	English
Pages (from-to)	2402-2404
Number of pages	3
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b900571d
Publication status	Published - 2009

Keywords / Materials (for Non-textual outputs)

PENTAVALENT-URANYL
ACTINYL IONS
CHEMISTRY
URANIUM
COORDINATION
COMPLEXES
MECHANISM
CP2UO
OXIDE
TH

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title = "A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment",

abstract = "A DFT study of the reduction and silylation of the uranyl U-O bond in a macrocyclic complex shows the importance of the initial dipotassiation in THF solution, and a slightly downhill reaction pathway for the oxo group functionalisation.",

keywords = "PENTAVALENT-URANYL, ACTINYL IONS, CHEMISTRY, URANIUM, COORDINATION, COMPLEXES, MECHANISM, CP2UO, OXIDE, TH",

author = "Ahmed Yahia and Arnold, {Polly L.} and Love, {Jason B.} and Laurent Maron",

year = "2009",

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journal = "Chemical Communications",

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AU - Love, Jason B.

AU - Maron, Laurent

PY - 2009

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KW - ACTINYL IONS

KW - CHEMISTRY

KW - URANIUM

KW - COORDINATION

KW - COMPLEXES

KW - MECHANISM

KW - CP2UO

KW - OXIDE

KW - TH

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JO - Chemical Communications

JF - Chemical Communications

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ER -

A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment

Abstract

Keywords / Materials (for Non-textual outputs)

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