A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

Alexandros Perivolaris, Constantinos C. Stoumpos, Jolanta Karpinska, Alan G. Ryder, Jamie M. Frost, Kevin Mason, Alessandro Prescimone, Alexandra M.Z. Slawin, Vadim G. Kessler, Jennifer S. Mathieson, Leroy Cronin, Euan K. Brechin*, Giannis S. Papaefstathiou

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η336-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Original languageEnglish
Pages (from-to)487-494
Number of pages8
JournalInorganic Chemistry Frontiers
Volume1
Issue number6
DOIs
Publication statusPublished - 1 Jun 2014

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