A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Farida H. Aidoudi; Lewis J. Downie; Russell E. Morris; Mark A. De Vries; Philip Lightfoot

doi:10.1039/c4dt00452c

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Farida H. Aidoudi, Lewis J. Downie, Russell E. Morris, Mark A. De Vries, Philip Lightfoot

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Abstract / Description of output

A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

Original language	English
Pages (from-to)	6304-6307
Journal	Dalton Transactions
Volume	43
Issue number	17
Early online date	13 Feb 2014
DOIs	https://doi.org/10.1039/c4dt00452c
Publication status	Published - 7 May 2014

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10.1039/c4dt00452c

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers
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abstract = "A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.",

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AU - A. De Vries, Mark

AU - Lightfoot, Philip

PY - 2014/5/7

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AB - A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

U2 - 10.1039/c4dt00452c

DO - 10.1039/c4dt00452c

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

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A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

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