A [Mn18] wheel-of-wheels

Marco Coletta, Thomais G. Tziotzi, Mark Gray, Gary S. Nichol, Mukesh K. Singh, Constantinos J. Milios, Euan K. Brechin

Research output: Contribution to journalArticlepeer-review

Abstract

A [Mn18] wheel of wheels is obtained from the reaction of MnBr2·4H2O and LH3 in MeOH. The metallic skeleton reveals two asymmetric [MnIII6MnII2] square wheels connected into a larger wheel via two MnII ions. Magnetic susceptibility and magnetisation data reveal competing exchange interactions, supported by computational studies.
Original languageEnglish
Pages (from-to)4122-4125
JournalChemical Communications
Volume2021
Issue number57
Early online date23 Mar 2021
DOIs
Publication statusE-pub ahead of print - 23 Mar 2021

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