A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1,4,8,11-tetraazacyclotetradecane-2,3-dione [exoO(2)]cyclam

L Cronin, A R Mount, S Parsons, N Robertson

Research output: Contribution to journalArticlepeer-review

Abstract

Synthesis of the new macrocycle 1,4,8,11-tetraazacyclo-tetradecane-2,3-dione [exoO(2)]cyclam and its complexation with copper(II) ion via the tetraaza groups and linked together through a copper(II) ion coordinated to the exo-cis oxygen donors of each macrocycle.

Original languageEnglish
Pages (from-to)1925-1927
Number of pages3
JournalDalton Transactions
Issue number12
Publication statusPublished - 21 Jun 1999

Keywords

  • OXPN = N,N'-BIS(3-AMINOPROPYL)OXAMIDE
  • CRYSTAL-STRUCTURE
  • COPPER(II)

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