A new class of single-molecule magnet: [Mn9O7(OAc)(11)(thme)(py)(3)(H2O)(2)] with an S=17/2 ground state

E K Brechin, M Soler, J Davidson, D N Hendrickson, S Parsons, G Christou

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of [Mn3O(OAc)(6)(py)(3)] with 1,1,1- tris(hydroxymethyl) ethane (H(3)thme) gives the Mn(IV)(3)Mn(III)(4)Mn(II)(2) complex [Mn9O7(OAc)(11)(thme)(py)(3)(H2O)(2)], which has an S = 17/2 ground state and displays strong out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.

Original languageEnglish
Pages (from-to)2252-2253
Number of pages2
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 2002

Keywords

  • CLUSTER

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