A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

John P. S. Mowat; Valerie R. Seymour; John M. Griffin; Stephen P. Thompson; Alexandra M. Z. Slawin; David Fairen-Jimenez; Tina Dueren; Sharon E. Ashbrook; Paul A. Wright

doi:10.1039/c1dt11729g

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO₂ adsorption

John P. S. Mowat, Valerie R. Seymour, John M. Griffin, Stephen P. Thompson, Alexandra M. Z. Slawin, David Fairen-Jimenez, Tina Dueren, Sharon E. Ashbrook, Paul A. Wright

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO₂ adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO₂.

Original language	English
Pages (from-to)	3937-3941
Number of pages	5
Journal	Dalton Transactions
Volume	41
Issue number	14
DOIs	https://doi.org/10.1039/c1dt11729g
Publication status	Published - 14 Apr 2012

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10.1039/c1dt11729g

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title = "A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption",

abstract = "The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.",

author = "Mowat, {John P. S.} and Seymour, {Valerie R.} and Griffin, {John M.} and Thompson, {Stephen P.} and Slawin, {Alexandra M. Z.} and David Fairen-Jimenez and Tina Dueren and Ashbrook, {Sharon E.} and Wright, {Paul A.}",

year = "2012",

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AU - Mowat, John P. S.

AU - Seymour, Valerie R.

AU - Griffin, John M.

AU - Thompson, Stephen P.

AU - Slawin, Alexandra M. Z.

AU - Fairen-Jimenez, David

AU - Dueren, Tina

AU - Ashbrook, Sharon E.

AU - Wright, Paul A.

PY - 2012/4/14

Y1 - 2012/4/14

N2 - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

AB - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

UR - http://www.scopus.com/inward/record.url?scp=84858721908&partnerID=8YFLogxK

U2 - 10.1039/c1dt11729g

DO - 10.1039/c1dt11729g

M3 - Article

SN - 1477-9226

VL - 41

SP - 3937

EP - 3941

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO₂ adsorption

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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO₂ adsorption