A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate

Christopher A. Cameron; David R. Allan; Konstantin V. Kamenev; Stephen A. Moggach; Mark Murrie; Simon Parsons

doi:10.1515/zkri-2013-1688

A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate

Christopher A. Cameron, David R. Allan, Konstantin V. Kamenev, Stephen A. Moggach, Mark Murrie, Simon Parsons^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

[Ni(en)(3)] [NO3](2) undergoes a displacive phase transition from P6(3)22 at ambient pressure to a lower symmetry P6(1)22/P6(5)22 structure between 0.82 and 0.87 GPa, which is characterized by a tripling of the unit cell c-axis and the number of molecules per unit cell. The same transition has been previously observed at 108 K. The application of pressure leads to a general shortening of O H hydrogen bonding interactions in the structure, with the greatest contraction (24%) occurring diagonally between stacks of Ni cation moieties and nitrate anions.

Original language	English
Pages (from-to)	200-209
Number of pages	10
Journal	Zeitschrift für Kristallographie - Crystalline Materials
Volume	229
Issue number	3
Early online date	10 Jan 2014
DOIs	https://doi.org/10.1515/zkri-2013-1688
Publication status	Published - Mar 2014

Keywords / Materials (for Non-textual outputs)

Phase transition
High pressure
Synchrotron radiation
Coordiniation chemistry

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10.1515/zkri-2013-1688

A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate
Copyright © 2014 by Walter de Gruyter Berlin Boston. This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License (CC BY-NC-ND 4.0), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Final published version, 1.39 MBLicence: Creative Commons: Attribution-NonCommercial-NoDerivatives (CC BY-NC-ND)

http://www.degruyter.com/view/j/zkri.2014.229.issue-3/zkri-2013-1688/zkri-2013-1688.xml

Pressure Sensitive Complexformation based on self assembling ligands
Parsons, S. (Principal Investigator), Jones, A. (Co-investigator), Kamenev, K. (Co-investigator) & Tasker, P. (Co-investigator)
EPSRC
1/03/09 → 29/08/12
Project: Research

Cite this

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title = "A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate",

abstract = "[Ni(en)(3)] [NO3](2) undergoes a displacive phase transition from P6(3)22 at ambient pressure to a lower symmetry P6(1)22/P6(5)22 structure between 0.82 and 0.87 GPa, which is characterized by a tripling of the unit cell c-axis and the number of molecules per unit cell. The same transition has been previously observed at 108 K. The application of pressure leads to a general shortening of O H hydrogen bonding interactions in the structure, with the greatest contraction (24%) occurring diagonally between stacks of Ni cation moieties and nitrate anions.",

keywords = "Phase transition, High pressure, Synchrotron radiation, Coordiniation chemistry",

author = "Cameron, {Christopher A.} and Allan, {David R.} and Kamenev, {Konstantin V.} and Moggach, {Stephen A.} and Mark Murrie and Simon Parsons",

year = "2014",

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doi = "10.1515/zkri-2013-1688",

language = "English",

volume = "229",

pages = "200--209",

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T1 - A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate

AU - Cameron, Christopher A.

AU - Allan, David R.

AU - Kamenev, Konstantin V.

AU - Moggach, Stephen A.

AU - Murrie, Mark

AU - Parsons, Simon

PY - 2014/3

Y1 - 2014/3

N2 - [Ni(en)(3)] [NO3](2) undergoes a displacive phase transition from P6(3)22 at ambient pressure to a lower symmetry P6(1)22/P6(5)22 structure between 0.82 and 0.87 GPa, which is characterized by a tripling of the unit cell c-axis and the number of molecules per unit cell. The same transition has been previously observed at 108 K. The application of pressure leads to a general shortening of O H hydrogen bonding interactions in the structure, with the greatest contraction (24%) occurring diagonally between stacks of Ni cation moieties and nitrate anions.

AB - [Ni(en)(3)] [NO3](2) undergoes a displacive phase transition from P6(3)22 at ambient pressure to a lower symmetry P6(1)22/P6(5)22 structure between 0.82 and 0.87 GPa, which is characterized by a tripling of the unit cell c-axis and the number of molecules per unit cell. The same transition has been previously observed at 108 K. The application of pressure leads to a general shortening of O H hydrogen bonding interactions in the structure, with the greatest contraction (24%) occurring diagonally between stacks of Ni cation moieties and nitrate anions.

KW - Phase transition

KW - High pressure

KW - Synchrotron radiation

KW - Coordiniation chemistry

U2 - 10.1515/zkri-2013-1688

DO - 10.1515/zkri-2013-1688

M3 - Article

SN - 2194-4946

VL - 229

SP - 200

EP - 209

JO - Zeitschrift für Kristallographie - Crystalline Materials

JF - Zeitschrift für Kristallographie - Crystalline Materials

IS - 3

ER -

A pressure-induced displacive phase transition in Tris(ethylenediamine) Nickel(II) nitrate

Abstract

Keywords / Materials (for Non-textual outputs)

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Pressure Sensitive Complexformation based on self assembling ligands

Cite this