A Ring Rearrangement Approach to the Synthesis of Benzo[b]quinolizine and Benzoindolizine Architectures

L. R. Donaldson, D. Haigh, A. N. Hulme

Research output: Contribution to journalArticlepeer-review

Abstract

An efficient ring rearrangement metathesis (RRM) approach to the synthesis of benzo[b]quinolizine and benzoindolizine systems from N-propargyl-phenanthridine derivatives is reported. A novel use of flash vacuum pyrolysis (FVP) for the Boc-deprotection of acid sensitive substrates is also disclosed.
Original languageEnglish
Pages (from-to)1587-1590
Number of pages4
Journal Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry
DOIs
Publication statusPublished - 2009

Keywords

  • phenanthridine
  • alkene
  • ring rearrangement metathesis
  • flash vacuum pyrolysis
  • skeletal diversity

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