A truncated [MnIII
12] tetrahedron from oxime-based [MnIII
3O] building blocks

J. M. Frost; S. Sanz; T. Rajeshkumar; M. B. Pitak; S. J. Coles; G. Rajaraman; W. Wernsdorfer; J. Schnack; P. J. Lusby; E. K. Brechin

doi:10.1039/c4dt01469c

A truncated [Mn^III ₁₂] tetrahedron from oxime-based [Mn^III ₃O] building blocks

J. M. Frost, S. Sanz, T. Rajeshkumar, M. B. Pitak, S. J. Coles, G. Rajaraman^*, W. Wernsdorfer, J. Schnack, P. J. Lusby, E. K. Brechin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The use of the novel pro-ligand H₄L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn^III ₁₂] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

Original language	English
Pages (from-to)	10690-10694
Number of pages	5
Journal	Dalton Transactions
Volume	43
Issue number	28
DOIs	https://doi.org/10.1039/c4dt01469c
Publication status	Published - 28 Jul 2014

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10.1039/c4dt01469c

A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocksAccepted author manuscript, 522 KB

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title = "A truncated [MnIII 12] tetrahedron from oxime-based [MnIII 3O] building blocks",

abstract = "The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII 12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.",

author = "Frost, {J. M.} and S. Sanz and T. Rajeshkumar and Pitak, {M. B.} and Coles, {S. J.} and G. Rajaraman and W. Wernsdorfer and J. Schnack and Lusby, {P. J.} and Brechin, {E. K.}",

year = "2014",

month = jul,

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doi = "10.1039/c4dt01469c",

language = "English",

volume = "43",

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journal = "Dalton Transactions",

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T1 - A truncated [MnIII 12] tetrahedron from oxime-based [MnIII 3O] building blocks

AU - Frost, J. M.

AU - Sanz, S.

AU - Rajeshkumar, T.

AU - Pitak, M. B.

AU - Coles, S. J.

AU - Rajaraman, G.

AU - Wernsdorfer, W.

AU - Schnack, J.

AU - Lusby, P. J.

AU - Brechin, E. K.

PY - 2014/7/28

Y1 - 2014/7/28

N2 - The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII 12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

AB - The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII 12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

UR - http://www.scopus.com/inward/record.url?scp=84903484575&partnerID=8YFLogxK

U2 - 10.1039/c4dt01469c

DO - 10.1039/c4dt01469c

M3 - Article

AN - SCOPUS:84903484575

VL - 43

SP - 10690

EP - 10694

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 28

ER -

A truncated [Mn^III ₁₂] tetrahedron from oxime-based [Mn^III ₃O] building blocks

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High Symmetry Paramagnetic Cages

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A truncated [MnIII 12] tetrahedron from oxime-based [MnIII 3O] building blocks

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High Symmetry Paramagnetic Cages

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A truncated [Mn^III ₁₂] tetrahedron from oxime-based [Mn^III ₃O] building blocks