Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Polly L. Arnold; Isobel A. Marr; Sergey Zlatogorsky; Ronan Bellabarba; Robert P. Tooze

doi:10.1039/c3dt52762j

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Polly L. Arnold^*, Isobel A. Marr, Sergey Zlatogorsky, Ronan Bellabarba, Robert P. Tooze

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A Sc NHC complex readily activates three equivalents of CO₂ showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS₂ is also activated by the labile carbenes, no metal involvement is observed.

Original language	English
Pages (from-to)	34-37
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	1
Early online date	28 Oct 2013
DOIs	https://doi.org/10.1039/c3dt52762j
Publication status	Published - 7 Jan 2014

Keywords

FRUSTRATED LEWIS PAIRS
SMALL-MOLECULE ACTIVATION
CO2
REACTIVITY
POLYMERIZATION
DITHIOCARBOXYLATES
CHEMISTRY
ADDUCTS
SOLIDS
BLOCK

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10.1039/c3dt52762j

Activation of Carbon Dioxide and Carbon Disulfide by a Scandium N- Heterocyclic Carbene Complex
Copyright © 2013 Royal Society of Chemistry. All rights reserved.
Accepted author manuscript, 864 KB

http://pubs.rsc.org/En/content/articlehtml/2014/dt/c3dt52762j

Clean catalysis for sustainable development
Love, J.
EPSRC
31/12/12 → 30/12/17
Project: Research

Cite this

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title = "Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex",

abstract = "A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.",

keywords = "FRUSTRATED LEWIS PAIRS, SMALL-MOLECULE ACTIVATION, CO2, REACTIVITY, POLYMERIZATION, DITHIOCARBOXYLATES, CHEMISTRY, ADDUCTS, SOLIDS, BLOCK",

author = "Arnold, {Polly L.} and Marr, {Isobel A.} and Sergey Zlatogorsky and Ronan Bellabarba and Tooze, {Robert P.}",

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doi = "10.1039/c3dt52762j",

language = "English",

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AU - Arnold, Polly L.

AU - Marr, Isobel A.

AU - Zlatogorsky, Sergey

AU - Bellabarba, Ronan

AU - Tooze, Robert P.

PY - 2014/1/7

Y1 - 2014/1/7

N2 - A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.

AB - A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.

KW - FRUSTRATED LEWIS PAIRS

KW - SMALL-MOLECULE ACTIVATION

KW - CO2

KW - REACTIVITY

KW - POLYMERIZATION

KW - DITHIOCARBOXYLATES

KW - CHEMISTRY

KW - ADDUCTS

KW - SOLIDS

KW - BLOCK

U2 - 10.1039/c3dt52762j

DO - 10.1039/c3dt52762j

M3 - Article

VL - 43

SP - 34

EP - 37

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 1

ER -

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Abstract

Keywords

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Clean catalysis for sustainable development

Cite this