Abstract / Description of output
Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen-nitrogen bonds and N-2 cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido derivatives are covered along with processes in which nitrogen-boron, nitrogen-silicon or nitrogen-carbon bonds can form. Although this review builds on previous publications, a general introduction to this field is included.
1 Introduction
1.1 Background
1.2 Coordination Chemistry of Dinitrogen
2 Dinitrogen Activation
3 Dinitrogen Cleavage
4 Reactivity of Coordinated Dinitrogen
4.1 Formation of N-H Bonds From Coordinated Dinitrogen
4.2 Formation of N-Element Bonds From Coordinated Dinitrogen
5 Final Thoughts.
Original language | English |
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Pages (from-to) | 1061-1076 |
Number of pages | 16 |
Journal | Advanced Synthesis & Catalysis |
Volume | 345 |
Issue number | 9-10 |
DOIs | |
Publication status | Published - Sept 2003 |