Aldehyde allylation with allylboronates providing alpha-addition products

Shue Kobayashi, Toshimitsu Endo, Uwe Schneider, Masaharu Ueno

Research output: Contribution to journalArticlepeer-review

Abstract

Zn(OH)(2)-catalyzed allylation reactions of allylboronates with aldehydes proceeded smoothly in aqueous media; when alpha-substituted allylboronates were employed, the a-addition products were obtained exclusively, and syn-adducts were formed selectively in most cases; the use of Zn(OH)(2) with dmp (ligand) in aqueous media is the key to these reactions.

Original languageEnglish
Pages (from-to)1260-1262
Number of pages3
JournalChemical Communications
Volume46
Issue number8
DOIs
Publication statusPublished - 2010

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