Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

Amy J. Challinor; Marc Calin; Gary S. Nichol; Neil B. Carter; Stephen P. Thomas

doi:10.1002/adsc.201600570

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

Amy J. Challinor, Marc Calin, Gary S. Nichol, Neil B. Carter, Stephen P. Thomas

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25–2 mol% iron catalyst and 1–25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.

Original language	English
Pages (from-to)	2404-2409
Journal	Advanced Synthesis & Catalysis
Volume	358
Issue number	15
Early online date	11 Jul 2016
DOIs	https://doi.org/10.1002/adsc.201600570
Publication status	Published - 28 Jul 2016

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title = "Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization",

abstract = "A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25–2 mol% iron catalyst and 1–25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.",

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AU - Calin, Marc

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AU - Carter, Neil B.

AU - Thomas, Stephen P.

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AB - A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25–2 mol% iron catalyst and 1–25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.

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Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

Abstract

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