Amine-bis(phenolate) Iron(III)-catalysed Formal Hydroamination of Olefins

Kailong Zhu; Michael Shaver; Stephen Thomas

doi:10.1002/asia.201501098

Amine-bis(phenolate) Iron(III)-catalysed Formal Hydroamination of Olefins

Kailong Zhu, Michael Shaver, Stephen Thomas

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report a practical synthesis of highly functionalised amines by the formal hydroamination reaction of alkenes with nitroarenes catalysed by an air stable amine-bis(phenolate) iron(III) complex. The reaction uses the easily handled phenylsilane, low catalyst loadings and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

Original language	English
Journal	Chemistry, an Asian journal
Early online date	11 Feb 2016
DOIs	https://doi.org/10.1002/asia.201501098
Publication status	E-pub ahead of print - 11 Feb 2016

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http://onlinelibrary.wiley.com/doi/10.1002/asia.201501098/abstract

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title = "Amine-bis(phenolate) Iron(III)-catalysed Formal Hydroamination of Olefins",

abstract = "We report a practical synthesis of highly functionalised amines by the formal hydroamination reaction of alkenes with nitroarenes catalysed by an air stable amine-bis(phenolate) iron(III) complex. The reaction uses the easily handled phenylsilane, low catalyst loadings and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).",

author = "Kailong Zhu and Michael Shaver and Stephen Thomas",

note = "{\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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AU - Zhu, Kailong

AU - Shaver, Michael

AU - Thomas, Stephen

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Y1 - 2016/2/11

N2 - We report a practical synthesis of highly functionalised amines by the formal hydroamination reaction of alkenes with nitroarenes catalysed by an air stable amine-bis(phenolate) iron(III) complex. The reaction uses the easily handled phenylsilane, low catalyst loadings and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

AB - We report a practical synthesis of highly functionalised amines by the formal hydroamination reaction of alkenes with nitroarenes catalysed by an air stable amine-bis(phenolate) iron(III) complex. The reaction uses the easily handled phenylsilane, low catalyst loadings and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

U2 - 10.1002/asia.201501098

DO - 10.1002/asia.201501098

M3 - Article

C2 - 26864731

SN - 1861-4728

JO - Chemistry, an Asian journal

JF - Chemistry, an Asian journal

ER -

Amine-bis(phenolate) Iron(III)-catalysed Formal Hydroamination of Olefins

Abstract

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