Abstract
The work presented here extends previous studies of amplified spontaneous emission (ASE) between ion-pair (charge-transfer) states of I-2 and shows that ASE can occur between states correlating with different states of the cation, namely, f0(g)(+)(P-3(0)) and D0(u)(+)(P-3(2)), despite the smaller transition dipole moment between them. A value of 0.34 e A is obtained for the transition dipole under experimental conditions where the f0(g)(+)(P-3(0))-> D0(u)(+)(P-3(2)) ASE is eliminated. No F0(u)(+)(P-3(0))
Original language | English |
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Article number | 124302 |
Number of pages | 8 |
Journal | The Journal of Chemical Physics |
Volume | 130 |
Issue number | 12 |
DOIs | |
Publication status | Published - 28 Mar 2009 |
Keywords / Materials (for Non-textual outputs)
- charge exchange
- Franck-Condon factors
- iodine
- molecular moments
- positive ions
- superradiance
- OPTICAL DOUBLE-RESONANCE
- NO RYDBERG STATES
- STIMULATED-EMISSION
- TRANSITIONS
- CONSTANTS
- SYSTEM
- P-3(2)
- I2