K( dibenzo- 18- crown- 6)[M(dmit) (2)](CH3CN)(2) (M = Ni, Au), which have a one- dimensional supramolecular array, have been prepared. These salts are isomorphous and each K+ (dibenzo- 18- crown- 6) suparamolecular cation unit is connected through the interaction of two CH3CN molecules. The [Ni(dmit)(2)] - molecules exist as isolated monomers, and the magnetic susceptibility of the salt exhibits Curie- type behavior.
|Pages (from-to)||art. no.-52|
|Number of pages||7|
|Publication status||Published - 2001|