An infinite supramolecular array structure in metal dithiolate complexes: crystal structure of K (dibenzo-18-crown-6)[M(dmit)(2)](CH3CN)(2) (M = Ni, Au)

K Shitagami, T Akutagawa, T Hasegawa, T Nakamura, N Robertson

Research output: Contribution to journalArticlepeer-review

Abstract

K( dibenzo- 18- crown- 6)[M(dmit) (2)](CH3CN)(2) (M = Ni, Au), which have a one- dimensional supramolecular array, have been prepared. These salts are isomorphous and each K+ (dibenzo- 18- crown- 6) suparamolecular cation unit is connected through the interaction of two CH3CN molecules. The [Ni(dmit)(2)] - molecules exist as isolated monomers, and the magnetic susceptibility of the salt exhibits Curie- type behavior.

Original languageEnglish
Pages (from-to)art. no.-52
Number of pages7
JournalCrystEngComm
Issue number52
Publication statusPublished - 2001

Keywords

  • TETRATHIAFULVALENE
  • TRANSITION
  • CATIONS
  • SALTS
  • DMIT

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