Arene-ligated heteroleptic terphenolate complexes of thorium

Jamie McKinven, Gary S. Nichol, Polly L. Arnold

Research output: Contribution to journalArticlepeer-review

Abstract

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.
Original languageEnglish
Pages (from-to)17416-17421
JournalDalton Transactions
Volume43
Issue number46
Early online date22 Oct 2014
DOIs
Publication statusPublished - 14 Dec 2014

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