Arene-ligated heteroleptic terphenolate complexes of thorium

Jamie McKinven; Gary S. Nichol; Polly L. Arnold

doi:10.1039/C4DT02995J

Arene-ligated heteroleptic terphenolate complexes of thorium

Jamie McKinven, Gary S. Nichol, Polly L. Arnold

Research output: Contribution to journal › Article › peer-review

Abstract

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.

Original language	English
Pages (from-to)	17416-17421
Journal	Dalton Transactions
Volume	43
Issue number	46
Early online date	22 Oct 2014
DOIs	https://doi.org/10.1039/C4DT02995J
Publication status	Published - 14 Dec 2014

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10.1039/C4DT02995J

Arene-ligated heteroleptic terphenolate complexes of thorium
Copyright © 2014 Royal Society of Chemistry. All rights reserved.
Accepted author manuscript, 612 KB

http://xlink.rsc.org/?DOI=C4DT02995J

Clean catalysis for sustainable development
Love, J. (Principal Investigator)
EPSRC
31/12/12 → 30/12/17
Project: Research
Hydrocarbon activation by f-block complexes
Arnold, P. (Principal Investigator)
EPSRC
1/10/09 → 31/05/15
Project: Research

Cite this

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title = "Arene-ligated heteroleptic terphenolate complexes of thorium",

abstract = "Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.",

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AB - Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.

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Arene-ligated heteroleptic terphenolate complexes of thorium

Abstract

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Projects

Clean catalysis for sustainable development

Hydrocarbon activation by f-block complexes

Cite this