Assembly of a calix[4]arene-supported (MnMnII)-Mn-III cluster mediated by halogen interactions

Stephanie M. Taylor*, Jamie M. Frost, Ross McLellan, Ruaraidh D. McIntosh, Euan K. Brechin, Scott J. Dalgarno

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A new calix[4]arene-supported (MnMnII)-Mn-III cluster, formed by the introduction of 3,5-dichlorobenzoate to a system known to afford (Mn2Mn2II)-Mn-III Single-Molecule Magnets (SMMs), assembles in a layered manner through halogen interactions; structural and magnetic properties of this new cluster are presented.

Original languageEnglish
Pages (from-to)8098-8101
Number of pages4
JournalCrystEngComm
Volume16
Issue number35
DOIs
Publication statusPublished - 2014

Keywords

  • TETRANUCLEAR MANGANESE(II) COMPLEXES
  • MAGNETIC-PROPERTIES
  • TRANSITION-METAL
  • CALIXARENES
  • CONSTRUCTION
  • MACROCYCLES
  • DERIVATIVES
  • CHEMISTRY
  • CAPSULES
  • ALKALI

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