Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis

P L  Arnold; M  Rodden; K M  Davis; A C  Scarisbrick; A J  Blake; C  Wilson; Polly Arnold

doi:10.1039/b404614e

Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis

P L Arnold, M Rodden, K M Davis, A C Scarisbrick, A J Blake, C Wilson, Polly Arnold

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

A one-pot synthesis of a wide range of bidentate, alkoxide-N-heterocyclic carbene ligands provides new lithium alkoxycarbenes and a range of covalently bound organometallic Cu(II) carbene complexes, which are catalytically active, in some cases enantioselectively, for conjugate addition reactions.

Original language	English
Pages (from-to)	1612-1613
Number of pages	2
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b404614e
Publication status	Published - 2004

Keywords / Materials (for Non-textual outputs)

CONJUGATE ADDITION
CHEMISTRY
TRANSFORMATIONS
LIGANDS
SILVER

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10.1039/b404614e

Cite this

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title = "Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis",

abstract = "A one-pot synthesis of a wide range of bidentate, alkoxide-N-heterocyclic carbene ligands provides new lithium alkoxycarbenes and a range of covalently bound organometallic Cu(II) carbene complexes, which are catalytically active, in some cases enantioselectively, for conjugate addition reactions.",

keywords = "CONJUGATE ADDITION, CHEMISTRY, TRANSFORMATIONS, LIGANDS, SILVER",

author = "Arnold, {P L} and M Rodden and Davis, {K M} and Scarisbrick, {A C} and Blake, {A J} and C Wilson and Polly Arnold",

year = "2004",

doi = "10.1039/b404614e",

language = "English",

pages = "1612--1613",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis

AU - Arnold, P L

AU - Rodden, M

AU - Davis, K M

AU - Scarisbrick, A C

AU - Blake, A J

AU - Wilson, C

AU - Arnold, Polly

PY - 2004

Y1 - 2004

N2 - A one-pot synthesis of a wide range of bidentate, alkoxide-N-heterocyclic carbene ligands provides new lithium alkoxycarbenes and a range of covalently bound organometallic Cu(II) carbene complexes, which are catalytically active, in some cases enantioselectively, for conjugate addition reactions.

AB - A one-pot synthesis of a wide range of bidentate, alkoxide-N-heterocyclic carbene ligands provides new lithium alkoxycarbenes and a range of covalently bound organometallic Cu(II) carbene complexes, which are catalytically active, in some cases enantioselectively, for conjugate addition reactions.

KW - CONJUGATE ADDITION

KW - CHEMISTRY

KW - TRANSFORMATIONS

KW - LIGANDS

KW - SILVER

U2 - 10.1039/b404614e

DO - 10.1039/b404614e

M3 - Article

SN - 1359-7345

SP - 1612

EP - 1613

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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