Atropisomeric phosphinines: design and synthesis

Christian Muller; Evgeny A. Pidko; Daniel Totev; Martin Lutz; Anthony L. Spek; Rutger A. van Santen; Dieter Vogt

doi:10.1039/b715197g

Atropisomeric phosphinines: design and synthesis

Christian Muller, Evgeny A. Pidko, Daniel Totev, Martin Lutz, Anthony L. Spek, Rutger A. van Santen, Dieter Vogt

Research output: Contribution to journal › Article › peer-review

Abstract

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent P-31{H-1} NMR spectroscopy.

Original language	English
Pages (from-to)	5372-5375
Number of pages	4
Journal	Dalton Transactions
Issue number	46
DOIs	https://doi.org/10.1039/b715197g
Publication status	Published - 2007

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title = "Atropisomeric phosphinines: design and synthesis",

abstract = "The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent P-31{H-1} NMR spectroscopy.",

author = "Christian Muller and Pidko, {Evgeny A.} and Daniel Totev and Martin Lutz and Spek, {Anthony L.} and {van Santen}, {Rutger A.} and Dieter Vogt",

year = "2007",

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AU - Pidko, Evgeny A.

AU - Totev, Daniel

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - van Santen, Rutger A.

AU - Vogt, Dieter

PY - 2007

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AB - The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent P-31{H-1} NMR spectroscopy.

U2 - 10.1039/b715197g

DO - 10.1039/b715197g

M3 - Article

SP - 5372

EP - 5375

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 46

ER -

Atropisomeric phosphinines: design and synthesis

Abstract

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