Atropisomeric phosphinines: design and synthesis

Christian Muller, Evgeny A. Pidko, Daniel Totev, Martin Lutz, Anthony L. Spek, Rutger A. van Santen, Dieter Vogt

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent P-31{H-1} NMR spectroscopy.

Original languageEnglish
Pages (from-to)5372-5375
Number of pages4
JournalDalton Transactions
Issue number46
Publication statusPublished - 2007


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