Projects per year
Abstract
The reduction of UVI uranyl halides or amides by simple LnII or UIII salts forms highly symmetrical, linear, oxo-bridged trinuclear UV-LnIII-UV, LnIII-UIV-LnIII and UIV-UIV-UIV complexes or linear LnIII-UV polymers according to the stoichiometry and solvent choice. Reactions can be tuned to give one- or two-electron uranyl reduction. Some features of their reactivity and magnetism are discussed in the context of using a series of strongly oxo-coupled homo and heterometallic poly(f-block) chains to better understand fundamental electronic structure in the f-block.
Original language | English |
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Journal | Angewandte Chemie International Edition |
Early online date | 7 Jul 2017 |
DOIs | |
Publication status | E-pub ahead of print - 7 Jul 2017 |
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Dive into the research topics of 'Axially Symmetric U-O-Ln and U-O-U containing molecules from the control of uranyl reduction with simple f-block halides'. Together they form a unique fingerprint.Projects
- 2 Finished
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FORTRESS: F block cOvalency and Reactivity defined by sTructural compRESSibility
Parsons, S. & Arnold, P.
1/07/16 → 30/06/20
Project: Research
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