Bismuth titanate modified and immobilized TiO2 photocatalysts for water purification: broad pollutant scope, ease of re-use and mechanistic studies

Gylen Odling, Zhi Yi Pong, Gavin Gilfillan, Colin R. Pulham, Neil Robertson

Research output: Contribution to journalArticlepeer-review

Abstract

Deposition of titanium dioxide (TiO2) coatings onto glass beads from a P25 enriched sol of titanium butoxide is described. This method gives a robust and stable covering, to which small bismuth containing clusters of 1–5 nm have been introduced using a simple and scalable sequential ionic layer adsorption reaction (SILAR) method. This bismuth-modified TiO2 coating has been proven to show significant improvements over the pristine TiO2 samples for a variety of different pollutants including intermediates in consumer product manufacture, pesticides, drugs and explosives. Using scavenger tests, the mechanism of degradation for each of the pollutant molecules tested has been probed, and a thorough discussion of the differences presented. The applicability of the system has also been assessed, with ease of re-use of the photocatalyst-bead apparatus investigated through recycling tests.
Original languageEnglish
JournalEnvironmental Science: Water Research & Technology
Early online date9 Nov 2018
DOIs
Publication statusE-pub ahead of print - 9 Nov 2018

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