Projects per year
Abstract / Description of output
Given the current interest in materials containing 1,4-azaborine units, the development of new routes to these structures is important. Carbonyl directed electrophilic borylation using BBr3 is a facile method for the ortho-borylation of N,N-diaryl-amide derivatives. Subsequent addition of Et3SiH results in carbonyl reduction and then formation of 1,4-azaborines that can be protected in situ using a Grignard reagent. Overall, borylation–reduction–borylation is a one-pot methodology to access 1,4-azaborines from simple precursors.
Original language | English |
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Journal | Organic letters |
Early online date | 6 Dec 2023 |
DOIs | |
Publication status | E-pub ahead of print - 6 Dec 2023 |
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Dive into the research topics of 'Borylation–Reduction–Borylation for the Formation of 1,4-Azaborines'. Together they form a unique fingerprint.Projects
- 1 Finished
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Enabling Catalytic Cross Couplings with only Zinc Electrophiles, Nucleophiles and Boranes
1/04/19 → 31/12/23
Project: Research