Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Stephanie M. Taylor; Ruaraidh D. McIntosh; Christine M. Beavers; Simon J. Teat; Stergios Piligkos; Scott J. Dalgarno; Euan K. Brechin

doi:10.1039/c0cc04466k

Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Stephanie M. Taylor, Ruaraidh D. McIntosh, Christine M. Beavers, Simon J. Teat, Stergios Piligkos, Scott J. Dalgarno, Euan K. Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

Original language	English
Pages (from-to)	1440-1442
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	5
DOIs	https://doi.org/10.1039/c0cc04466k
Publication status	Published - 2011

Keywords / Materials (for Non-textual outputs)

VALENCE MNIIMNIII COMPLEXES
CALIXARENES
CAPSULES
METAL
MAGNETS

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10.1039/c0cc04466k

Cite this

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title = "Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers",

abstract = "Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.",

keywords = "VALENCE MNIIMNIII COMPLEXES, CALIXARENES, CAPSULES, METAL, MAGNETS",

author = "Taylor, {Stephanie M.} and McIntosh, {Ruaraidh D.} and Beavers, {Christine M.} and Teat, {Simon J.} and Stergios Piligkos and Dalgarno, {Scott J.} and Brechin, {Euan K.}",

year = "2011",

doi = "10.1039/c0cc04466k",

language = "English",

volume = "47",

pages = "1440--1442",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

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TY - JOUR

T1 - Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

AU - Taylor, Stephanie M.

AU - McIntosh, Ruaraidh D.

AU - Beavers, Christine M.

AU - Teat, Simon J.

AU - Piligkos, Stergios

AU - Dalgarno, Scott J.

AU - Brechin, Euan K.

PY - 2011

Y1 - 2011

N2 - Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

AB - Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

KW - VALENCE MNIIMNIII COMPLEXES

KW - CALIXARENES

KW - CAPSULES

KW - METAL

KW - MAGNETS

UR - http://www.scopus.com/inward/record.url?scp=78751523198&partnerID=8YFLogxK

U2 - 10.1039/c0cc04466k

DO - 10.1039/c0cc04466k

M3 - Article

SN - 1359-7345

VL - 47

SP - 1440

EP - 1442

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Abstract

Keywords / Materials (for Non-textual outputs)

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Calixarenes: Metal-organic frameworks and discrete superstructures

Supramolecular synthesis of molecular clusters: Topological control of hybrid nanomagnets

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Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Abstract

Keywords / Materials (for Non-textual outputs)

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Other files and links

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Projects

Calixarenes: Metal-organic frameworks and discrete superstructures

Supramolecular synthesis of molecular clusters: Topological control of hybrid nanomagnets

Cite this