Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.

Lauren Evelyn Connor; Carole Morrison; Iain D H Oswald; Colin R Pulham; Mark R Warren

doi:10.1039/C7SC01379E

Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.

Lauren Evelyn Connor, Carole Morrison, Iain D H Oswald, Colin R Pulham, Mark R Warren

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.

Original language	English
Pages (from-to)	4872-4878
Number of pages	7
Journal	Chemical Science
Volume	8
Issue number	7
Early online date	4 May 2017
DOIs	https://doi.org/10.1039/C7SC01379E
Publication status	Published - Jul 2017

Keywords / Materials (for Non-textual outputs)

GAMMA-CYCLOTRIMETHYLENE TRINITRAMINE
CONDENSED-PHASE DECOMPOSITION
ENERGETIC MATERIALS
LOW-TEMPERATURE
RAMAN-SPECTRA
CO-CRYSTALS
SOLID CO2
X-RAY
1,3,5-TRINITROHEXAHYDRO-S-TRIAZINE
COCRYSTALLIZATION

Access to Document

10.1039/C7SC01379ELicence: Creative Commons: Attribution (CC-BY)

20170505 Morrison CO2N2O_ESI_resubmissionAccepted author manuscript, 371 KBLicence: Creative Commons: Attribution (CC-BY)

http://pubs.rsc.org/en/Content/ArticleLanding/2017/SC/C7SC01379E

Colin Pulham
- School of Chemistry - Personal Chair in High-Pressure
- EaStCHEM
Person: Academic: Research Active

Cite this

@article{7edfd20c318846a7819a0baf396d00fb,

title = "Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.",

abstract = "A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.",

keywords = "GAMMA-CYCLOTRIMETHYLENE TRINITRAMINE, CONDENSED-PHASE DECOMPOSITION, ENERGETIC MATERIALS, LOW-TEMPERATURE, RAMAN-SPECTRA, CO-CRYSTALS, SOLID CO2, X-RAY, 1,3,5-TRINITROHEXAHYDRO-S-TRIAZINE, COCRYSTALLIZATION",

author = "Connor, {Lauren Evelyn} and Carole Morrison and Oswald, {Iain D H} and Pulham, {Colin R} and Warren, {Mark R}",

year = "2017",

month = jul,

doi = "10.1039/C7SC01379E",

language = "English",

volume = "8",

pages = "4872--4878",

journal = "Chemical Science",

issn = "2041-6539",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.

AU - Connor, Lauren Evelyn

AU - Morrison, Carole

AU - Oswald, Iain D H

AU - Pulham, Colin R

AU - Warren, Mark R

PY - 2017/7

Y1 - 2017/7

N2 - A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.

AB - A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.

KW - GAMMA-CYCLOTRIMETHYLENE TRINITRAMINE

KW - CONDENSED-PHASE DECOMPOSITION

KW - ENERGETIC MATERIALS

KW - LOW-TEMPERATURE

KW - RAMAN-SPECTRA

KW - CO-CRYSTALS

KW - SOLID CO2

KW - X-RAY

KW - 1,3,5-TRINITROHEXAHYDRO-S-TRIAZINE

KW - COCRYSTALLIZATION

U2 - 10.1039/C7SC01379E

DO - 10.1039/C7SC01379E

M3 - Article

SN - 2041-6539

VL - 8

SP - 4872

EP - 4878

JO - Chemical Science

JF - Chemical Science

IS - 7

ER -

Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure.

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

Access to Document

Fingerprint

Profiles

Colin Pulham

Cite this