Abstract
Spontaneous reaction of carbon monoxide with cyclotrisilenes has been observed. Depending on the substitution pattern, the initial product of carbonylation either dimerizes or can be trapped to yield highly functionalized cyclic silenes.
Original language | English |
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Pages (from-to) | 13247-13250 |
Number of pages | 4 |
Journal | Angewandte Chemie International Edition |
Volume | 52 |
Issue number | 50 |
Early online date | 7 Nov 2013 |
DOIs | |
Publication status | Published - 9 Dec 2013 |
Keywords / Materials (for Non-textual outputs)
- carbonylation
- double bonds
- silicon
- small-molecule activation
- small rings
- PAUSON-KHAND REACTION
- CARBON-MONOXIDE
- COMPLEX
- HYDROFORMYLATION
- REDUCTION
- MOLECULES
- CARBENES
- MATRICES
- CO