Carbonylation of Cyclotrisilenes

Michael J. Cowley, Yu Ohmori, Volker Huch, Masaaki Ichinohe, Akira Sekiguchi*, David Scheschkewitz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Spontaneous reaction of carbon monoxide with cyclotrisilenes has been observed. Depending on the substitution pattern, the initial product of carbonylation either dimerizes or can be trapped to yield highly functionalized cyclic silenes.
Original languageEnglish
Pages (from-to)13247-13250
Number of pages4
JournalAngewandte Chemie International Edition
Volume52
Issue number50
Early online date7 Nov 2013
DOIs
Publication statusPublished - 9 Dec 2013

Keywords

  • carbonylation
  • double bonds
  • silicon
  • small-molecule activation
  • small rings
  • PAUSON-KHAND REACTION
  • CARBON-MONOXIDE
  • COMPLEX
  • HYDROFORMYLATION
  • REDUCTION
  • MOLECULES
  • CARBENES
  • MATRICES
  • CO

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