Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

Agustin Jimenez-Aquino; Emmanuel Ferrer Flegeau; Uwe Schneider; Shu Kobayashi

doi:10.1039/c1cc13348a

Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

Agustin Jimenez-Aquino, Emmanuel Ferrer Flegeau, Uwe Schneider, Shu Kobayashi

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and gamma-selectivity; the use of boronates proved to be crucial in terms of reactivity.

Original language	English
Pages (from-to)	9456-9458
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	33
DOIs	https://doi.org/10.1039/c1cc13348a
Publication status	Published - 2011

Access to Document

10.1039/c1cc13348a

Cite this

@article{4fb00d5499194e7299afdaba4ce99d3b,

title = "Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates",

abstract = "We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and gamma-selectivity; the use of boronates proved to be crucial in terms of reactivity.",

author = "Agustin Jimenez-Aquino and Flegeau, {Emmanuel Ferrer} and Uwe Schneider and Shu Kobayashi",

year = "2011",

doi = "10.1039/c1cc13348a",

language = "English",

volume = "47",

pages = "9456--9458",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "33",

}

TY - JOUR

T1 - Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

AU - Jimenez-Aquino, Agustin

AU - Flegeau, Emmanuel Ferrer

AU - Schneider, Uwe

AU - Kobayashi, Shu

PY - 2011

Y1 - 2011

N2 - We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and gamma-selectivity; the use of boronates proved to be crucial in terms of reactivity.

AB - We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and gamma-selectivity; the use of boronates proved to be crucial in terms of reactivity.

U2 - 10.1039/c1cc13348a

DO - 10.1039/c1cc13348a

M3 - Article

SN - 1359-7345

VL - 47

SP - 9456

EP - 9458

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

Abstract / Description of output

Access to Document

Fingerprint

Cite this