Chemoselective Hydrogenation of Functionalized Nitroarenes using Supported Mo Promoted Pt Nanoparticles

Evert Boymans; Susan Boland; Peter T. Witte; Christian Mueller; Dieter Vogt

doi:10.1002/cctc.201200437

Chemoselective Hydrogenation of Functionalized Nitroarenes using Supported Mo Promoted Pt Nanoparticles

Evert Boymans, Susan Boland, Peter T. Witte, Christian Mueller, Dieter Vogt^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

Positive discrimination: Supported MoVI promoted Pt nanoparticles (c-Pt+Mo/C) are successfully applied as catalysts in the chemoselective hydrogenation of functionalized nitroarenes. Mild conditions (30 °C, 4 bar H2, EtOH) prove sufficient for complete reduction to the corresponding anilines, leaving other functional groups untouched. Turnover numbers of at least 20 000 show that this catalyst is very tolerant to halogen-containing aromatics.

Original language	English
Pages (from-to)	431-434
Number of pages	4
Journal	ChemCatChe
Volume	5
Issue number	2
DOIs	https://doi.org/10.1002/cctc.201200437
Publication status	Published - Feb 2013

Keywords / Materials (for Non-textual outputs)

CATALYTIC-HYDROGENATION
heterogeneous catalysis
chemoselectivity
platinum
reduction
nanoparticles

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title = "Chemoselective Hydrogenation of Functionalized Nitroarenes using Supported Mo Promoted Pt Nanoparticles",

abstract = " Positive discrimination: Supported MoVI promoted Pt nanoparticles (c-Pt+Mo/C) are successfully applied as catalysts in the chemoselective hydrogenation of functionalized nitroarenes. Mild conditions (30 °C, 4 bar H2, EtOH) prove sufficient for complete reduction to the corresponding anilines, leaving other functional groups untouched. Turnover numbers of at least 20 000 show that this catalyst is very tolerant to halogen-containing aromatics.",

keywords = "CATALYTIC-HYDROGENATION, heterogeneous catalysis, chemoselectivity, platinum, reduction, nanoparticles",

author = "Evert Boymans and Susan Boland and Witte, {Peter T.} and Christian Mueller and Dieter Vogt",

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T1 - Chemoselective Hydrogenation of Functionalized Nitroarenes using Supported Mo Promoted Pt Nanoparticles

AU - Boymans, Evert

AU - Boland, Susan

AU - Witte, Peter T.

AU - Mueller, Christian

AU - Vogt, Dieter

PY - 2013/2

Y1 - 2013/2

N2 - Positive discrimination: Supported MoVI promoted Pt nanoparticles (c-Pt+Mo/C) are successfully applied as catalysts in the chemoselective hydrogenation of functionalized nitroarenes. Mild conditions (30 °C, 4 bar H2, EtOH) prove sufficient for complete reduction to the corresponding anilines, leaving other functional groups untouched. Turnover numbers of at least 20 000 show that this catalyst is very tolerant to halogen-containing aromatics.

AB - Positive discrimination: Supported MoVI promoted Pt nanoparticles (c-Pt+Mo/C) are successfully applied as catalysts in the chemoselective hydrogenation of functionalized nitroarenes. Mild conditions (30 °C, 4 bar H2, EtOH) prove sufficient for complete reduction to the corresponding anilines, leaving other functional groups untouched. Turnover numbers of at least 20 000 show that this catalyst is very tolerant to halogen-containing aromatics.

KW - CATALYTIC-HYDROGENATION

KW - heterogeneous catalysis

KW - chemoselectivity

KW - platinum

KW - reduction

KW - nanoparticles

U2 - 10.1002/cctc.201200437

DO - 10.1002/cctc.201200437

M3 - Article

SN - 1867-3880

VL - 5

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EP - 434

JO - ChemCatChe

JF - ChemCatChe

IS - 2

ER -

Chemoselective Hydrogenation of Functionalized Nitroarenes using Supported Mo Promoted Pt Nanoparticles

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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