Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles

Takuya Shiga; Kazuya Maruyama; Graham N. Newton; Ross Inglis; Euan K. Brechin; Hiroki Oshio

doi:10.1021/ic5002418

Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles

Takuya Shiga, Kazuya Maruyama, Graham N. Newton, Ross Inglis, Euan K. Brechin^*, Hiroki Oshio

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The one-dimensional complex [Mn(III)2Cu(II)(mu(3)-O)(Cl-sao)(3)(EtOH)(2)]center dot EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn-3(III)(mu(3)-O)-Cl-2(Cl-sao)(3)(MeOH)(2)(H2O)(2)] with [Cu(acac)(2)]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.

Original language	English
Pages (from-to)	4272-4274
Number of pages	3
Journal	Inorganic Chemistry
Volume	53
Issue number	9
Early online date	17 Apr 2014
DOIs	https://doi.org/10.1021/ic5002418
Publication status	Published - 5 May 2014

Keywords / Materials (for Non-textual outputs)

MOLECULE MAGNETS
ANISOTROPY
MAGNETIZATION
FERRIMAGNET
NETWORKS
CATIONS
COMPLEX
MN
CO
CU

Access to Document

10.1021/ic5002418

140326_ReviseSubmitted manuscript, 2.07 MB

Molecular Magnets: From Cages to Supramolecular Assemblies
Brechin, E. (Principal Investigator)
EPSRC
1/10/13 → 30/09/16
Project: Research

Cite this

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title = "Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles",

abstract = "The one-dimensional complex [Mn(III)2Cu(II)(mu(3)-O)(Cl-sao)(3)(EtOH)(2)]center dot EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn-3(III)(mu(3)-O)-Cl-2(Cl-sao)(3)(MeOH)(2)(H2O)(2)] with [Cu(acac)(2)]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.",

keywords = "MOLECULE MAGNETS, ANISOTROPY, MAGNETIZATION, FERRIMAGNET, NETWORKS, CATIONS, COMPLEX, MN, CO, CU",

author = "Takuya Shiga and Kazuya Maruyama and Newton, {Graham N.} and Ross Inglis and Brechin, {Euan K.} and Hiroki Oshio",

year = "2014",

month = may,

day = "5",

doi = "10.1021/ic5002418",

language = "English",

volume = "53",

pages = "4272--4274",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Chiral Single-Chain Magnet

T2 - Helically Stacked [(Mn2CuII)-Cu-III] Triangles

AU - Shiga, Takuya

AU - Maruyama, Kazuya

AU - Newton, Graham N.

AU - Inglis, Ross

AU - Brechin, Euan K.

AU - Oshio, Hiroki

PY - 2014/5/5

Y1 - 2014/5/5

N2 - The one-dimensional complex [Mn(III)2Cu(II)(mu(3)-O)(Cl-sao)(3)(EtOH)(2)]center dot EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn-3(III)(mu(3)-O)-Cl-2(Cl-sao)(3)(MeOH)(2)(H2O)(2)] with [Cu(acac)(2)]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.

AB - The one-dimensional complex [Mn(III)2Cu(II)(mu(3)-O)(Cl-sao)(3)(EtOH)(2)]center dot EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn-3(III)(mu(3)-O)-Cl-2(Cl-sao)(3)(MeOH)(2)(H2O)(2)] with [Cu(acac)(2)]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.

KW - MOLECULE MAGNETS

KW - ANISOTROPY

KW - MAGNETIZATION

KW - FERRIMAGNET

KW - NETWORKS

KW - CATIONS

KW - COMPLEX

KW - MN

KW - CO

KW - CU

U2 - 10.1021/ic5002418

DO - 10.1021/ic5002418

M3 - Article

C2 - 24742003

SN - 0020-1669

VL - 53

SP - 4272

EP - 4274

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 9

ER -

Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles

Abstract

Keywords / Materials (for Non-textual outputs)

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Projects

Molecular Magnets: From Cages to Supramolecular Assemblies

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