Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles

Takuya Shiga, Kazuya Maruyama, Graham N. Newton, Ross Inglis, Euan K. Brechin*, Hiroki Oshio

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

The one-dimensional complex [Mn(III)2Cu(II)(mu(3)-O)(Cl-sao)(3)(EtOH)(2)]center dot EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn-3(III)(mu(3)-O)-Cl-2(Cl-sao)(3)(MeOH)(2)(H2O)(2)] with [Cu(acac)(2)]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.

Original languageEnglish
Pages (from-to)4272-4274
Number of pages3
JournalInorganic Chemistry
Volume53
Issue number9
Early online date17 Apr 2014
DOIs
Publication statusPublished - 5 May 2014

Keywords / Materials (for Non-textual outputs)

  • MOLECULE MAGNETS
  • ANISOTROPY
  • MAGNETIZATION
  • FERRIMAGNET
  • NETWORKS
  • CATIONS
  • COMPLEX
  • MN
  • CO
  • CU

Fingerprint

Dive into the research topics of 'Chiral Single-Chain Magnet: Helically Stacked [(Mn2CuII)-Cu-III] Triangles'. Together they form a unique fingerprint.

Cite this