Chloride ion effects on kinetic resolution in Pd-catalysed allylic alkylation

GC Lloyd-Jones, SC Stephen

Research output: Contribution to journalArticlepeer-review

Abstract

Chloride ion (5 mol%) accelerates and stabilises the oxidative addition of the slow-reacting enantiomer of cyclopentenyl pivaloate to Pd-o complexes bearing the Trost modular ligand.

Original languageEnglish
Pages (from-to)2321-2322
Number of pages2
JournalChemical Communications
Issue number21
Publication statusPublished - 7 Nov 1998

Keywords

  • HECK REACTIONS
  • PALLADIUM
  • COMPLEXES
  • LIGANDS
  • ENANTIOSELECTIVITY
  • MECHANISM
  • AMINATION
  • SITE

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