CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron

Thomas N. Hooper; Ross Inglis; Maria A. Palacios; Gary S. Nichol; Mateusz B. Pitak; Simon J. Coles; Giulia Lorusso; Marco Evangelisti; Euan K. Brechin

doi:10.1039/c4cc00141a

CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron

Thomas N. Hooper, Ross Inglis, Maria A. Palacios, Gary S. Nichol, Mateusz B. Pitak, Simon J. Coles, Giulia Lorusso, Marco Evangelisti^*, Euan K. Brechin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.

Original language	English
Pages (from-to)	3498-3500
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	26
DOIs	https://doi.org/10.1039/c4cc00141a
Publication status	Published - 2014

Keywords

SINGLE-MOLECULE MAGNETS
CRYSTAL-STRUCTURE
NICKEL(II) COMPLEX
SODALITE TOPOLOGY
ATMOSPHERIC CO2
CLUSTERS
LN
REFRIGERANTS
NETWORKS
FIXATION

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10.1039/c4cc00141a

Gd6Cu3 paper_18th DecSubmitted manuscript, 1.56 MB

Molecular Magnets: From Cages to Supramolecular Assemblies
Brechin, E.
EPSRC
1/10/13 → 30/09/16
Project: Research

Cite this

@article{983de41b95344e56954d778f9b1901de,

title = "CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron",

abstract = "A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.",

keywords = "SINGLE-MOLECULE MAGNETS, CRYSTAL-STRUCTURE, NICKEL(II) COMPLEX, SODALITE TOPOLOGY, ATMOSPHERIC CO2, CLUSTERS, LN, REFRIGERANTS, NETWORKS, FIXATION",

author = "Hooper, {Thomas N.} and Ross Inglis and Palacios, {Maria A.} and Nichol, {Gary S.} and Pitak, {Mateusz B.} and Coles, {Simon J.} and Giulia Lorusso and Marco Evangelisti and Brechin, {Euan K.}",

year = "2014",

doi = "10.1039/c4cc00141a",

language = "English",

volume = "50",

pages = "3498--3500",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "26",

}

TY - JOUR

T1 - CO2 as a reaction ingredient for the construction of metal cages

T2 - a carbonate-panelled [Gd6Cu3] tridiminished icosahedron

AU - Hooper, Thomas N.

AU - Inglis, Ross

AU - Palacios, Maria A.

AU - Nichol, Gary S.

AU - Pitak, Mateusz B.

AU - Coles, Simon J.

AU - Lorusso, Giulia

AU - Evangelisti, Marco

AU - Brechin, Euan K.

PY - 2014

Y1 - 2014

N2 - A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.

AB - A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.

KW - SINGLE-MOLECULE MAGNETS

KW - CRYSTAL-STRUCTURE

KW - NICKEL(II) COMPLEX

KW - SODALITE TOPOLOGY

KW - ATMOSPHERIC CO2

KW - CLUSTERS

KW - LN

KW - REFRIGERANTS

KW - NETWORKS

KW - FIXATION

U2 - 10.1039/c4cc00141a

DO - 10.1039/c4cc00141a

M3 - Article

C2 - 24557013

VL - 50

SP - 3498

EP - 3500

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 26

ER -

CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron

Abstract

Keywords

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Molecular Magnets: From Cages to Supramolecular Assemblies

Cite this