Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

Jingying Peng; Jamie H. Docherty; Andrew P. Dominey; Stephen P. Thomas

doi:10.1039/C7CC01085K

Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

Jingying Peng, Jamie H. Docherty, Andrew P. Dominey, Stephen P. Thomas

School of Chemistry

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Abstract / Description of output

A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98:2 branched:linear selectivity (24 examples, 45-92% isolated yield).

Original language	English
Pages (from-to)	4726-4729
Journal	Chemical Communications
Volume	53
Issue number	34
Early online date	12 Apr 2017
DOIs	https://doi.org/10.1039/C7CC01085K
Publication status	E-pub ahead of print - 12 Apr 2017

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10.1039/C7CC01085KLicence: Creative Commons: Attribution Non-Commercial (CC-BY-NC)

20170503 Thomas Cobalt-Catalysed Markovnikov Selective Hydroboration of VinylarenesAccepted author manuscript, 207 KBLicence: Creative Commons: Attribution Non-Commercial (CC-BY-NC)

http://xlink.rsc.org/?DOI=C7CC01085K

Stephen Thomas
- School of Chemistry - Personal Chair of Sustainable Catalysis
- EaStCHEM
Person: Academic: Research Active

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@article{9001f6f2fb47422699d019bdb3ad0f05,

title = "Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes",

abstract = "A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98:2 branched:linear selectivity (24 examples, 45-92% isolated yield).",

author = "Jingying Peng and Docherty, {Jamie H.} and Dominey, {Andrew P.} and Thomas, {Stephen P.}",

year = "2017",

month = apr,

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doi = "10.1039/C7CC01085K",

language = "English",

volume = "53",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

AU - Peng, Jingying

AU - Docherty, Jamie H.

AU - Dominey, Andrew P.

AU - Thomas, Stephen P.

PY - 2017/4/12

Y1 - 2017/4/12

N2 - A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98:2 branched:linear selectivity (24 examples, 45-92% isolated yield).

AB - A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98:2 branched:linear selectivity (24 examples, 45-92% isolated yield).

U2 - 10.1039/C7CC01085K

DO - 10.1039/C7CC01085K

M3 - Article

SN - 1359-7345

VL - 53

SP - 4726

EP - 4729

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

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Stephen Thomas

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