Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2](-) (M = Au, Ag)

Sergio Sanz; Jamie M. Frost; Giulia Lorusso; Marco Evangelisti; Mateusz B. Pitak; Simon J. Coles; Gary S. Nichol; Euan K. Brechin

doi:10.1039/c3dt53502a

Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2](-) (M = Au, Ag)

Sergio Sanz, Jamie M. Frost, Giulia Lorusso, Marco Evangelisti, Mateusz B. Pitak, Simon J. Coles, Gary S. Nichol, Euan K. Brechin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The linear [M(CN)2](-) (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [Mn(III)6] single-molecule magnets (SMMs).

Original language	English
Pages (from-to)	4622-4625
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	12
DOIs	https://doi.org/10.1039/c3dt53502a
Publication status	Published - 2014

Keywords

SINGLE-MOLECULE MAGNETS
BUILDING-BLOCK
COMPLEXES

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10.1039/c3dt53502a

manuscriptSubmitted manuscript, 3.23 MB

Molecular Magnets: From Cages to Supramolecular Assemblies
Brechin, E.
EPSRC
1/10/13 → 30/09/16
Project: Research

Cite this

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title = "Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2](-) (M = Au, Ag)",

abstract = "The linear [M(CN)2](-) (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [Mn(III)6] single-molecule magnets (SMMs).",

keywords = "SINGLE-MOLECULE MAGNETS, BUILDING-BLOCK, COMPLEXES",

author = "Sergio Sanz and Frost, {Jamie M.} and Giulia Lorusso and Marco Evangelisti and Pitak, {Mateusz B.} and Coles, {Simon J.} and Nichol, {Gary S.} and Brechin, {Euan K.}",

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doi = "10.1039/c3dt53502a",

language = "English",

volume = "43",

pages = "4622--4625",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T2 - 1D chains of [Mn6] SMMs from [M(CN)2](-) (M = Au, Ag)

AU - Sanz, Sergio

AU - Frost, Jamie M.

AU - Lorusso, Giulia

AU - Evangelisti, Marco

AU - Pitak, Mateusz B.

AU - Coles, Simon J.

AU - Nichol, Gary S.

AU - Brechin, Euan K.

PY - 2014

Y1 - 2014

N2 - The linear [M(CN)2](-) (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [Mn(III)6] single-molecule magnets (SMMs).

AB - The linear [M(CN)2](-) (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [Mn(III)6] single-molecule magnets (SMMs).

KW - SINGLE-MOLECULE MAGNETS

KW - BUILDING-BLOCK

KW - COMPLEXES

U2 - 10.1039/c3dt53502a

DO - 10.1039/c3dt53502a

M3 - Article

C2 - 24477355

VL - 43

SP - 4622

EP - 4625

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 12

ER -

Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2](-) (M = Au, Ag)

Abstract

Keywords

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Projects

Molecular Magnets: From Cages to Supramolecular Assemblies

Cite this