Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

Ross McLellan; Stephanie M. Taylor; Ruaraidh D. McIntosh; Euan K. Brechin; Scott J. Dalgarno

doi:10.1039/c3dt50294e

Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn^IVMn^III dimer

Ross McLellan, Stephanie M. Taylor, Ruaraidh D. McIntosh, Euan K. Brechin^*, Scott J. Dalgarno

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH₂) have been utilised in the facile synthesis of a Mn^IIIMn^IV dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

Original language	English
Pages (from-to)	6697-6700
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	19
DOIs	https://doi.org/10.1039/c3dt50294e
Publication status	Published - 21 May 2013

Keywords

FAMILY
SINGLE-MOLECULE MAGNETS
CLUSTERS
COMPLEXES

Access to Document

10.1039/c3dt50294e

PDF available here
Copyright © 2013 by the Royal Society of Chemistry. All rights reserved.
Accepted author manuscript, 506 KB

http://pubs.rsc.org/en/Content/ArticleLanding/2013/DT/c3dt50294e#!divAbstract

1 Finished

Calixarenes: Metal-organic frameworks and discrete superstructures
Brechin, E.
EPSRC
1/08/11 → 31/07/14
Project: Research

Cite this

@article{ad3323d9a9fb47a1aaa0e4ac2834b2a2,

title = "Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer",

abstract = "A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH2) have been utilised in the facile synthesis of a MnIIIMnIV dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.",

keywords = "FAMILY, SINGLE-MOLECULE MAGNETS, CLUSTERS, COMPLEXES",

author = "Ross McLellan and Taylor, {Stephanie M.} and McIntosh, {Ruaraidh D.} and Brechin, {Euan K.} and Dalgarno, {Scott J.}",

year = "2013",

month = may,

day = "21",

doi = "10.1039/c3dt50294e",

language = "English",

volume = "42",

pages = "6697--6700",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

AU - McLellan, Ross

AU - Taylor, Stephanie M.

AU - McIntosh, Ruaraidh D.

AU - Brechin, Euan K.

AU - Dalgarno, Scott J.

PY - 2013/5/21

Y1 - 2013/5/21

N2 - A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH2) have been utilised in the facile synthesis of a MnIIIMnIV dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

AB - A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH2) have been utilised in the facile synthesis of a MnIIIMnIV dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

KW - FAMILY

KW - SINGLE-MOLECULE MAGNETS

KW - CLUSTERS

KW - COMPLEXES

U2 - 10.1039/c3dt50294e

DO - 10.1039/c3dt50294e

M3 - Article

VL - 42

SP - 6697

EP - 6700

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 19

ER -

Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

Abstract

Keywords

Access to Document

Fingerprint

Projects

Calixarenes: Metal-organic frameworks and discrete superstructures

Cite this

Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn^IVMn^III dimer