Compression of Fe3C to 30 GPa at room temperature

J Li; HK Mao; Y Fei; E Gregoryanz; M Eremets; CS Zha

doi:10.1007/s00269-001-0224-4

Compression of Fe3C to 30 GPa at room temperature

J Li^*, HK Mao, Y Fei, E Gregoryanz, M Eremets, CS Zha

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

Polycrystalline Fe3C (cementite) was compressed in a neon pressure medium to 30.5 GPa at 300 K using diamond-anvil cell techniques. Angular dispersive X-ray diffraction of Fe3C was measured using monochromatic synchrotron radiation and imaging plates. No phase transition was observed up to the highest pressure studied. The pressure-volume data were fitted to a third-order Birch-Murnaghan equation of state. With V-0 constrained to a measured value of 155.28 Angstrom(3), the best fit yielded a 300-K isothermal bulk modulus K-0 = 174 +/- 6 GPa, and its pressure derivative at constant temperature K-0' = (partial derivativeK(0)/partial derivativeP)(T) = 4.8 +/- 0.8.

Original language	English
Pages (from-to)	166-169
Number of pages	4
Journal	Physics and Chemistry of Minerals
Volume	29
Issue number	3
DOIs	https://doi.org/10.1007/s00269-001-0224-4
Publication status	Published - 1 Apr 2002

Keywords / Materials (for Non-textual outputs)

Fe3C
high pressure
phase stability
bulk modulus
EoS
PRESSURE
EQUATION
STATE
CALIBRATION
SOLIDS
CARBON
MEDIA
NEON
CORE

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10.1007/s00269-001-0224-4

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title = "Compression of Fe3C to 30 GPa at room temperature",

abstract = "Polycrystalline Fe3C (cementite) was compressed in a neon pressure medium to 30.5 GPa at 300 K using diamond-anvil cell techniques. Angular dispersive X-ray diffraction of Fe3C was measured using monochromatic synchrotron radiation and imaging plates. No phase transition was observed up to the highest pressure studied. The pressure-volume data were fitted to a third-order Birch-Murnaghan equation of state. With V-0 constrained to a measured value of 155.28 Angstrom(3), the best fit yielded a 300-K isothermal bulk modulus K-0 = 174 +/- 6 GPa, and its pressure derivative at constant temperature K-0' = (partial derivativeK(0)/partial derivativeP)(T) = 4.8 +/- 0.8.",

keywords = "Fe3C, high pressure, phase stability, bulk modulus, EoS, PRESSURE, EQUATION, STATE, CALIBRATION, SOLIDS, CARBON, MEDIA, NEON, CORE",

author = "J Li and HK Mao and Y Fei and E Gregoryanz and M Eremets and CS Zha",

year = "2002",

month = apr,

day = "1",

doi = "10.1007/s00269-001-0224-4",

language = "English",

volume = "29",

pages = "166--169",

journal = "Physics and Chemistry of Minerals",

issn = "0342-1791",

publisher = "Springer",

number = "3",

}

TY - JOUR

T1 - Compression of Fe3C to 30 GPa at room temperature

AU - Li, J

AU - Mao, HK

AU - Fei, Y

AU - Gregoryanz, E

AU - Eremets, M

AU - Zha, CS

PY - 2002/4/1

Y1 - 2002/4/1

N2 - Polycrystalline Fe3C (cementite) was compressed in a neon pressure medium to 30.5 GPa at 300 K using diamond-anvil cell techniques. Angular dispersive X-ray diffraction of Fe3C was measured using monochromatic synchrotron radiation and imaging plates. No phase transition was observed up to the highest pressure studied. The pressure-volume data were fitted to a third-order Birch-Murnaghan equation of state. With V-0 constrained to a measured value of 155.28 Angstrom(3), the best fit yielded a 300-K isothermal bulk modulus K-0 = 174 +/- 6 GPa, and its pressure derivative at constant temperature K-0' = (partial derivativeK(0)/partial derivativeP)(T) = 4.8 +/- 0.8.

AB - Polycrystalline Fe3C (cementite) was compressed in a neon pressure medium to 30.5 GPa at 300 K using diamond-anvil cell techniques. Angular dispersive X-ray diffraction of Fe3C was measured using monochromatic synchrotron radiation and imaging plates. No phase transition was observed up to the highest pressure studied. The pressure-volume data were fitted to a third-order Birch-Murnaghan equation of state. With V-0 constrained to a measured value of 155.28 Angstrom(3), the best fit yielded a 300-K isothermal bulk modulus K-0 = 174 +/- 6 GPa, and its pressure derivative at constant temperature K-0' = (partial derivativeK(0)/partial derivativeP)(T) = 4.8 +/- 0.8.

KW - Fe3C

KW - high pressure

KW - phase stability

KW - bulk modulus

KW - EoS

KW - PRESSURE

KW - EQUATION

KW - STATE

KW - CALIBRATION

KW - SOLIDS

KW - CARBON

KW - MEDIA

KW - NEON

KW - CORE

U2 - 10.1007/s00269-001-0224-4

DO - 10.1007/s00269-001-0224-4

M3 - Article

SN - 0342-1791

VL - 29

SP - 166

EP - 169

JO - Physics and Chemistry of Minerals

JF - Physics and Chemistry of Minerals

IS - 3

ER -

Compression of Fe3C to 30 GPa at room temperature

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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