TY - JOUR
T1 - Continuity of heavy Rydberg behaviour in the ungerade ion-pair states of H 2
AU - Chartrand, Alexander M.
AU - Donovan, Robert J.
AU - Lawley, Kenneth P.
AU - Mccormack, Elizabeth F.
PY - 2017/3/22
Y1 - 2017/3/22
N2 - Heavy Rydberg behaviour and absolute quantum defects are reported for resonances in the ungerade manifold of H2 above the (1s,3l)(1s,3l) dissociation limit. The continuity of the vibrational progression of the View the MathML sourceB″B¯ state through the crossing with the 3p3p asymptote is demonstrated and a predominantly diabatic picture of the vibrational motion emerges, indicating that the ion-pair resonances possess little View the MathML source61Σu+ state character.
AB - Heavy Rydberg behaviour and absolute quantum defects are reported for resonances in the ungerade manifold of H2 above the (1s,3l)(1s,3l) dissociation limit. The continuity of the vibrational progression of the View the MathML sourceB″B¯ state through the crossing with the 3p3p asymptote is demonstrated and a predominantly diabatic picture of the vibrational motion emerges, indicating that the ion-pair resonances possess little View the MathML source61Σu+ state character.
U2 - 10.1016/j.cplett.2017.03.058
DO - 10.1016/j.cplett.2017.03.058
M3 - Article
SN - 0009-2614
VL - 676
SP - 140
EP - 143
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -