Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state

D J  White; L  Cronin; S  Parsons; N  Robertson; P A  Tasker; A P  Bisson

Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state

D J White, L Cronin, S Parsons, N Robertson, P A Tasker, A P Bisson

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

The high density and strength of intermolecular hydrogen bonding between amine and sulfonamide units in the complex [Cu(Tstn)(2)] [TstnH = N-(3-aminopropyl)-4-methylbenzenesulfonamide] give rise to energetically unfavourable coordination geometries at the copper centres in the solid state, in a manner analogous to the entatic state forced on metal active sites in metalloenzymes through secondary and tertiary protein structures.

Original language	English
Pages (from-to)	1107-1108
Number of pages	2
Journal	Chemical Communications
Issue number	12
Publication status	Published - 21 Jun 1999

Cite this

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title = "Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state",

abstract = "The high density and strength of intermolecular hydrogen bonding between amine and sulfonamide units in the complex [Cu(Tstn)(2)] [TstnH = N-(3-aminopropyl)-4-methylbenzenesulfonamide] give rise to energetically unfavourable coordination geometries at the copper centres in the solid state, in a manner analogous to the entatic state forced on metal active sites in metalloenzymes through secondary and tertiary protein structures.",

author = "White, {D J} and L Cronin and S Parsons and N Robertson and Tasker, {P A} and Bisson, {A P}",

year = "1999",

month = jun,

day = "21",

language = "English",

pages = "1107--1108",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "12",

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TY - JOUR

T1 - Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state

AU - White, D J

AU - Cronin, L

AU - Parsons, S

AU - Robertson, N

AU - Tasker, P A

AU - Bisson, A P

PY - 1999/6/21

Y1 - 1999/6/21

N2 - The high density and strength of intermolecular hydrogen bonding between amine and sulfonamide units in the complex [Cu(Tstn)(2)] [TstnH = N-(3-aminopropyl)-4-methylbenzenesulfonamide] give rise to energetically unfavourable coordination geometries at the copper centres in the solid state, in a manner analogous to the entatic state forced on metal active sites in metalloenzymes through secondary and tertiary protein structures.

AB - The high density and strength of intermolecular hydrogen bonding between amine and sulfonamide units in the complex [Cu(Tstn)(2)] [TstnH = N-(3-aminopropyl)-4-methylbenzenesulfonamide] give rise to energetically unfavourable coordination geometries at the copper centres in the solid state, in a manner analogous to the entatic state forced on metal active sites in metalloenzymes through secondary and tertiary protein structures.

M3 - Article

SN - 1359-7345

SP - 1107

EP - 1108

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state

Abstract / Description of output

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