Abstract / Description of output
Three new complexes of the type Mn(NN)(CO)(3)Br have been synthesized, where NN = 5-substituted-1,10-phenanthroline. The novel compounds have been characterized by H-1 NMR, FTIR, CV, HRMS, and UV/Vis, as well as X-ray crystallography in one case. The known NN = phenanthroline compound, and four analogous Re(I) compounds are also presented; their photophysical and electrochemical properties are discussed. A correlation is apparent between the MLCT absorbance bands and the electrochemical reduction of both the Re and Mn series of compounds. (C) 2014 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 22-26 |
Number of pages | 5 |
Journal | Inorganica Chimica Acta |
Volume | 427 |
DOIs | |
Publication status | Published - 1 Mar 2015 |
Keywords / Materials (for Non-textual outputs)
- Electrochemistry
- Rhenium compounds
- Manganese compounds
- Metal-carbonyl
- Phenanthroline ligand
- DENSITY-FUNCTIONAL THEORY
- CO2 REDUCTION
- EXCITED-STATE
- RE(I) COMPLEXES
- TRICARBONYL
- MANGANESE
- RHENIUM
- ELECTROCATALYSTS
- ABSORPTION
- CATALYSTS