Co₃Mo₃N—An efficient multifunctional electrocatalyst

Efficient catalysts are required for both oxidative and reductive reactions of hydrogen and oxygen in sustainable energy conversion devices. However, current precious metal-based electrocatalysts do not perform well across the full range of reactions and reported multifunctional catalysts are all complex hybrids. Here, we show that single-phase porous Co₃Mo₃N prepared via a facile method is an efficient and reliable electrocatalyst for three essential energy conversion reactions; oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and hydrogen evolution reaction (HER) in alkaline solutions. Co₃Mo₃N presents outstanding OER, ORR, and HER activity with high durability, comparable with the commercial catalysts RuO₂ for OER and Pt/C for ORR and HER. In practical demonstrations, Co₃Mo₃N gives high specific capacity (850 mA h g_Zn⁻¹ at 10 mA cm⁻²) as the cathode in a zinc-air battery, and a low potential (1.63 V at 10 mA cm⁻²) used in a water-splitting electrolyzer. Availability of Co and Mo d-states appear to result in high ORR and HER performance, while the OER properties result from a cobalt oxide-rich activation surface layer. Our findings will inspire further development of bimetallic nitrides as cost-effective and versatile multifunctional catalysts that will enable scalable usage of electrochemical energy devices.