[Cr(III)8M(II)6](12+) Coordination Cubes (M(II) =Cu, Co)

Sergio Sanz; Helen M O'Connor; Eufemio Moreno Pineda; Kasper S Pedersen; Gary S Nichol; Ole Mønsted; Høgni Weihe; Stergios Piligkos; Eric J L McInnes; Paul J Lusby; Euan K Brechin

doi:10.1002/anie.201501041

[Cr(III)8M(II)6](12+) Coordination Cubes (M(II) =Cu, Co)

Sergio Sanz, Helen M O'Connor, Eufemio Moreno Pineda, Kasper S Pedersen, Gary S Nichol, Ole Mønsted, Høgni Weihe, Stergios Piligkos, Eric J L McInnes, Paul J Lusby, Euan K Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

[Cr(III) 8 M(II) 6 ](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a "naked" M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.

Original language	English
Pages (from-to)	6761–6764
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	54
Issue number	23
Early online date	17 Apr 2015
DOIs	https://doi.org/10.1002/anie.201501041
Publication status	Published - 1 Jun 2015

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10.1002/anie.201501041

Sanz_et_al-2015-Angewandte_Chemie_International_EditionFinal published version, 1.09 MB

Molecular Magnets: From Cages to Supramolecular Assemblies
Brechin, E.
EPSRC
1/10/13 → 30/09/16
Project: Research

Euan Brechin
- E.Brechined.acuk
- School of Chemistry - Personal Chair in Coordination Chemistry
- EaStCHEM
Person: Academic: Research Active

Cite this

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title = "[Cr(III)8M(II)6](12+) Coordination Cubes (M(II) =Cu, Co)",

abstract = "[Cr(III) 8 M(II) 6 ](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a {"}naked{"} M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.",

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year = "2015",

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doi = "10.1002/anie.201501041",

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pages = "6761–6764",

journal = "Angewandte Chemie International Edition",

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T1 - [Cr(III)8M(II)6](12+) Coordination Cubes (M(II) =Cu, Co)

AU - Sanz, Sergio

AU - O'Connor, Helen M

AU - Pineda, Eufemio Moreno

AU - Pedersen, Kasper S

AU - Nichol, Gary S

AU - Mønsted, Ole

AU - Weihe, Høgni

AU - Piligkos, Stergios

AU - McInnes, Eric J L

AU - Lusby, Paul J

AU - Brechin, Euan K

PY - 2015/6/1

Y1 - 2015/6/1

N2 - [Cr(III) 8 M(II) 6 ](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a "naked" M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.

AB - [Cr(III) 8 M(II) 6 ](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a "naked" M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.

U2 - 10.1002/anie.201501041

DO - 10.1002/anie.201501041

M3 - Article

C2 - 25891167

VL - 54

SP - 6761

EP - 6764

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 23

ER -

[Cr(III)8M(II)6](12+) Coordination Cubes (M(II) =Cu, Co)

Abstract

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Molecular Magnets: From Cages to Supramolecular Assemblies

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