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Cobalt catalysis enables a new method for the generation of zinc enolates using diethylzinc to reduce alpha,ss-unsaturated amides. This method has been applied to a high-yielding diastereoselective reductive aldol cyclization.
- REFORMATSKY-TYPE REACTION
- ALPHA,BETA-UNSATURATED CARBOXAMIDES
- ENANTIOSELECTIVE SYNTHESIS
FingerprintDive into the research topics of 'Diastereoselective cobalt-catalyzed reductive aldol cyclizations using diethylzinc as the stoichiometric reductant'. Together they form a unique fingerprint.
- 1 Finished
4/04/05 → 30/09/07