Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

Caroline E. Knapp; Claire J. Carmalt; Paul F. McMillan; Derek A. Wann; Heather E. Robertson; David W. H. Rankin

doi:10.1039/b817893n

Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

Caroline E. Knapp, Claire J. Carmalt, Paul F. McMillan, Derek A. Wann, Heather E. Robertson, David W. H. Rankin

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the vapour produced upon heating the dimethylalkoxygallane [Me₂GaOCH₂CH₂NMe₂]₂ has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me₂GaOCH₂CH₂NMe₂] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.

Original language	English
Pages (from-to)	6880-6882
Number of pages	3
Journal	Dalton Transactions
Issue number	48
DOIs	https://doi.org/10.1039/b817893n
Publication status	Published - Oct 2008

Keywords

CHEMICAL-VAPOR-DEPOSITION
OXIDE THIN-FILMS
HETEROMETALLIC ALKOXIDES
PRECURSORS
ALCOHOLS
MOCVD
CVD

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10.1039/b817893n

Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structureFinal published version, 107 KB

http://pubs.rsc.org/en/Content/ArticleLanding/2008/DT/b817893n

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title = "Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure",

abstract = "The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.",

keywords = "CHEMICAL-VAPOR-DEPOSITION, OXIDE THIN-FILMS, HETEROMETALLIC ALKOXIDES, PRECURSORS, ALCOHOLS, MOCVD, CVD",

author = "Knapp, {Caroline E.} and Carmalt, {Claire J.} and McMillan, {Paul F.} and Wann, {Derek A.} and Robertson, {Heather E.} and Rankin, {David W. H.}",

year = "2008",

month = oct,

doi = "10.1039/b817893n",

language = "English",

pages = "6880--6882",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

AU - Knapp, Caroline E.

AU - Carmalt, Claire J.

AU - McMillan, Paul F.

AU - Wann, Derek A.

AU - Robertson, Heather E.

AU - Rankin, David W. H.

PY - 2008/10

Y1 - 2008/10

N2 - The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.

AB - The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.

KW - CHEMICAL-VAPOR-DEPOSITION

KW - OXIDE THIN-FILMS

KW - HETEROMETALLIC ALKOXIDES

KW - PRECURSORS

KW - ALCOHOLS

KW - MOCVD

KW - CVD

UR - http://www.scopus.com/inward/record.url?scp=57349124413&partnerID=8YFLogxK

U2 - 10.1039/b817893n

DO - 10.1039/b817893n

M3 - Article

SP - 6880

EP - 6882

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 48

ER -

Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

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Keywords

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